Solid-State Synthesis and Crystal Structure of Cubic-Type Cluster Complex[Bu4N]3[WAg3S4I4]

Abstract

Abstract: The title compound was prepared from the solid-state reaction of (NH₄)₂WS₄,AgIand Bu4NBr at low-heating temperature(90℃), then crystallized from CH₂Cl₂/acetone/n-pentane(1:2 :2).The orange crystal belongs to the cubic system with space group P43m,a=b=c=1.2304(2)nm,V=1.8629(9)nm³,Dc=1.69 g/cm³,Z=1.The final Ris 0.0835 for 270 reflections.The anion core of the title compound can be considered as a cubic skeleton composed of one Mo atom,three Ag atoms,four Satoms and one Iatom which are arranged in disorder.

Key words: W-Ag-S cluster, Cubic-type structure, Solid-state synthesis at low-heating temperature, Crystal structure

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TANG Ka-Luo, NI HAi-Hong, JIN Xiang-Lin, TANG You-Qi . Solid-State Synthesis and Crystal Structure of Cubic-Type Cluster Complex[Bu₄N]₃[WAg₃S₄I₄][J]. Chem. J. Chinese Universities, 1994, 15(3): 315.

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Solid-State Synthesis and Crystal Structure of Cubic-Type Cluster Complex[Bu₄N]₃[WAg₃S₄I₄]

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