The Structure and Catalytic Behaviour of Co-Mo-Te System in the Oxidation of tertButyl Alcohol

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (12): 1845.

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The Structure and Catalytic Behaviour of Co-Mo-Te System in the Oxidation of tertButyl Alcohol

WANG Guo-Jia, WU Tong-Hao, YANG Hong-Mao, JIANG Yu-Zi, JI Yu-Shu

Department of Chemistry, Jilin University, Changchun, 130023

Received:1994-02-19 Revised:1994-05-05 Online:1994-12-24 Published:1994-12-24

Abstract

Abstract: The Co-Mo-Te system catalysts were prepared and chracterized by IRand XRD.The catalytic behaviour of Co-Mo-Te systems were studied in the tert-butyl alcohol oxidation reaction. The results indicate that the new phases of Co₄TeMo₃O₁₆ and MoO₃ are formed with introducing Te into Co-Mo systems.There exists some relationship between the conversion of tert-butyl alcohol, selectivity of oxidation products (MAL+MAAand Sco_x) and these new phases.

Key words: Co-Mo-Te-O systems, tert-butyl alcohol, Oxidation

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WANG Guo-Jia, WU Tong-Hao, YANG Hong-Mao, JIANG Yu-Zi, JI Yu-Shu. The Structure and Catalytic Behaviour of Co-Mo-Te System in the Oxidation of tertButyl Alcohol[J]. Chem. J. Chinese Universities, 1994, 15(12): 1845.

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The Structure and Catalytic Behaviour of Co-Mo-Te System in the Oxidation of tertButyl Alcohol

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