The Steady State Electrochemical Behavior of Homogeneous Catalytic Reactions at Microelectrodes of Any Given Geometry

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (11): 1682.

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The Steady State Electrochemical Behavior of Homogeneous Catalytic Reactions at Microelectrodes of Any Given Geometry

SU Lian-Yong, LUO Jin, LIN Zhong-Hua, TIAN Zhao-Wu

Department of Chemistry, Xiamen University, Xiamen, 361005

Received:1993-01-21 Revised:1994-05-26 Online:1994-11-24 Published:1994-11-24

Abstract

Abstract: The steady state electrochemical behavior of the pseudo-first and second order homogeneous catalytic reactions at a microelectrode of any given geometry is discussed in this paper.The mathematical treatment of the microelectrode using the concept of reaction layer is simple and is possible to avoid using complicated mathematical skills, By using these equations, some methods for determining kinetic parameters for the pseudo first order and second order CE'reactions are presented.

Key words: Microelectrode, Reaction layer, Homogeneous catalytic reaction, Steady stateelectrochemical behavior

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SU Lian-Yong, LUO Jin, LIN Zhong-Hua, TIAN Zhao-Wu. The Steady State Electrochemical Behavior of Homogeneous Catalytic Reactions at Microelectrodes of Any Given Geometry[J]. Chem. J. Chinese Universities, 1994, 15(11): 1682.

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The Steady State Electrochemical Behavior of Homogeneous Catalytic Reactions at Microelectrodes of Any Given Geometry

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