Synthesis and Structure of 3,4-Diphenyl-1,3,4-diazaphospholidin-2-thione-4-oxides(sulfides)

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (9): 1244.

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Synthesis and Structure of 3,4-Diphenyl-1,3,4-diazaphospholidin-2-thione-4-oxides(sulfides)

FENG Ke-Sheng¹, CHEN Ru-Yu¹, WANG Hong-Gen², WANG Ru-Ji²

1. Institute of Elemento-Org.Chem., Nankai Univ., Tianjin, 300071;
2. Central laboratory, Nankai University

Received:1993-01-13 Revised:1993-04-05 Online:1993-09-24 Published:1993-09-24

Abstract

Abstract: The mannich-type reactions of phenylthiourea with phenyl dichlorophosphine and aldehydes (ketones) are investigated.Besides the expected products, 3,4-diphenyl-1,3,4-diaza-phospholidin-2-thione-4-oxides, small amounts of new products, the corresponding 4-sulfides were isolated and characterized.Some structure information of the products are disclosed.Amechanism involving addition of P-Hto the imine derivatives is proposed for the reactions.

Key words: Mannich-type reaction, Synthesis, 1,3,4-diazaphospholidin-2-thione, Reaction mechanism

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FENG Ke-Sheng, CHEN Ru-Yu, WANG Hong-Gen, WANG Ru-Ji. Synthesis and Structure of 3,4-Diphenyl-1,3,4-diazaphospholidin-2-thione-4-oxides(sulfides)[J]. Chem. J. Chinese Universities, 1993, 14(9): 1244.

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Synthesis and Structure of 3,4-Diphenyl-1,3,4-diazaphospholidin-2-thione-4-oxides(sulfides)

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