Studies on the Solid State Reaction of Coordination.Compounds (LXI) --Solid State Synthesis of [Cu(SC(Ph)NHPh)(PPh3)2X](X=Cl, Br, I) and Crystal Structures of [Cu(SC(Ph)NHPh)(PPh3)2Cl]

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (6): 750.

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Studies on the Solid State Reaction of Coordination.Compounds (LXI) --Solid State Synthesis of [Cu(SC(Ph)NHPh)(PPh₃)₂X](X=Cl, Br, I) and Crystal Structures of [Cu(SC(Ph)NHPh)(PPh₃)₂Cl]

LANG Jian-Ping¹, BAO Shi-An¹, XIN Xin-Quan¹, CAI Jin-Hua², KANG Bei-Sheng²

1. Coordination Chemistry Institute, Nanjing University, Nanjing, 210008;
2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou

Received:1992-09-09 Revised:1992-11-22 Online:1993-06-24 Published:1993-06-24

Abstract

Abstract: Areddish-yellow solid was produced by the solid state reaction of SC(PH)NHPh, CuX(X=Cl,Br,I) and PPh₃.The products were extracted with CS₂ to obtain the reddish-yellow cubic crystals [Cu(SC(Ph)NHPh)(PPh₃)₂X].The crystal (X=Cl) is monoclinic with α=1.8013(5) nm, 6=1.4588(5) nm, c=1.7222(5) nm;β=105.54(3)°, space group P2₁/c, Z=-4.The geometry of the central Cu(Ⅰ) ion is distorted tetrahedron configuration.The average bond angle about the Cu(Ⅰ) ion is 109.4% Cu-S, Cu- Cl, Cu-P(1) and Cu--P(2) distances are 0.2352(3) nm, 0.2375(4) nm, 0.2297(4) nm and 0.2282(3) nm, respectively.

Key words: Solid state synthesis, Crystal structure, [Cu(SC(Ph)NHPh)(PPh₃)₂X], Distorted tetrahedron configuration

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LANG Jian-Ping, BAO Shi-An, XIN Xin-Quan, CAI Jin-Hua, KANG Bei-Sheng. Studies on the Solid State Reaction of Coordination.Compounds (LXI) --Solid State Synthesis of [Cu(SC(Ph)NHPh)(PPh₃)₂X](X=Cl, Br, I) and Crystal Structures of [Cu(SC(Ph)NHPh)(PPh₃)₂Cl][J]. Chem. J. Chinese Universities, 1993, 14(6): 750.

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Studies on the Solid State Reaction of Coordination.Compounds (LXI) --Solid State Synthesis of [Cu(SC(Ph)NHPh)(PPh₃)₂X](X=Cl, Br, I) and Crystal Structures of [Cu(SC(Ph)NHPh)(PPh₃)₂Cl]

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