Crystal Structures of 1,3,2-Oxazaphospholidine Derivatives

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (4): 536.

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Crystal Structures of 1,3,2-Oxazaphospholidine Derivatives

LIU Xiao-Lan¹, SUN Ming¹, MIAO Fang-Ming¹, YANG Hua-Zheng², SHAO Jiu-Shu², WANG Hui-Lin², CHEN Ru-Yu²

1. Department of Chemistry, Tianjm Normal University, Tianjin, 300074;
2. Institute of Elemento-Organic Chemistry, Nankai University, Tianjin

Received:1992-03-11 Revised:1993-01-30 Online:1993-04-24 Published:1993-04-24

Abstract

Abstract: The crystal and molecular structures of 2-diethylamino-3-(4'-methylbenzoyl)-2-thione-l, 3, 2-oxazaphospholidine (1) and 2-diethylamino-3-(2', 4'-dichlorobenzoyl)-2-thione-1,3, 2-oxaza-phospholidine(2) were determined by X-ray diffraction method.The diffraction data were collected on a CAD4 single crystal diffractometer.The crystallographic data are as follows; (1) C₁₄H₂₁N₂O₂PS, orthorhombic, space group Pbca α=0.9057(5) nm, 6=1.3974(6) nm, c=2.5130(7) nm, Z=8, V=3.1806 nm³, R=0.051.(2) C₁₃H₁₇N₂O₂PSCl₂, monoclinic, space group P2₁/c, α=0.7375(1) nm, 6=1.4370(3) nm, c=l.6015(7) nm, β=93.70(2)°/, Z=4, V=1.6895 nm³, R=0.054.The structures of the two compounds were solved by the direct method.The five-membered oxaza-phospholidine ring has a half chair conformation in both of the molecules.

Key words: Crystal structure, 1,3,2-Oxazaphospholidine, Insecticide

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LIU Xiao-Lan, SUN Ming, MIAO Fang-Ming, YANG Hua-Zheng, SHAO Jiu-Shu, WANG Hui-Lin, CHEN Ru-Yu. Crystal Structures of 1,3,2-Oxazaphospholidine Derivatives[J]. Chem. J. Chinese Universities, 1993, 14(4): 536.

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Crystal Structures of 1,3,2-Oxazaphospholidine Derivatives

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