Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (10): 1473.

• Articles • Previous Articles     Next Articles

Measurement of Relative Reactivity Ratios of Styrene and BMA by FTIR

LU Zhi-Bao, CHEN Jing, HAN Zhe-Wen, WU Ping-Ping   

  1. 1. Dept.of Polymer Sci.and Eng., East China Univ.of Sci.and Techn., Shanghai, 200237;
    2. Structure Research Labor., Univ.of Sci.and Techn.of China
  • Received:1992-10-20 Revised:1993-05-03 Online:1993-10-24 Published:1993-10-24

Abstract: For the system of styrene/n-butyl methacrylate/AIBN, copolymerizations were carried out at 40℃, 60℃, 80℃, 100℃, 120℃, 140℃ respectively.The compositions of copoly-mers were analyzed by FTIR.The relative reactivity ratios of St and BMAare calculated by the error-in variables method, and 95% joint confidence intervals of the reactivity ratios are also given.The relative reactivity ratios of St-BMAsystem at different temperatures were obtained from the linear relation of relative reactivity rarios and temperatures by regression treatment.

Key words: Relative reactivity ratio, FTIR, St-BMA

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