Studies on Synthetic Bilayer Membranes Containing Naphthalene Chromophore

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (1): 97.

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Studies on Synthetic Bilayer Membranes Containing Naphthalene Chromophore

LIU Chun-Jing¹, LI Guo-Wen¹, TIAN Yong-Chi¹, LIANG Ying-Qiu²

1. Instititeof Theoretical Chemistry, Jilin University, Changchun;
2. Department of Chemistry, Nanjing University, Nanjing, 210008

Received:1992-03-10 Revised:1992-08-25 Online:1993-01-24 Published:1993-01-24

Abstract

Abstract: Aseries of single-chain naphthalene containing amphiphiles, C.Naph(2,6)C₄N⁺ (CH₃)₃ (n= 16,12,7,4), C₁₂Naph(2,6)C₄N⁺(CH₃)₂CH₂CH₂OHandC₁₂Naph(2,6)PO₄^- were systematically synthesized.The aggregate morphology of the amphiphiles in dilute aqueous solution was observed by electron microscopy.The gel-to-liquid crystal phase transition of the bilayer membranes was studied by means of differential scanning calorimmetry(DSC).¹H NMRresults of the aqueous bilayers are used to investigate the molecular motion in the membranes.The self-organization properties are discussed for the series of amphiphiles in dilute aqueous solution.

Key words: Synthetic bilayer membrane, Vesicle, Amphiphile

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LIU Chun-Jing, LI Guo-Wen, TIAN Yong-Chi, LIANG Ying-Qiu. Studies on Synthetic Bilayer Membranes Containing Naphthalene Chromophore[J]. Chem. J. Chinese Universities, 1993, 14(1): 97.

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Studies on Synthetic Bilayer Membranes Containing Naphthalene Chromophore

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