Studies on the Solid State Reactions of Coordination Compounds (XLIX)——Solid State Synthesis and Crystal Structure of [(n-Bu)4N]3[Mo4S4Cl4]

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (9): 1173.

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Studies on the Solid State Reactions of Coordination Compounds (XLIX)——Solid State Synthesis and Crystal Structure of [(n-Bu)₄N]₃[Mo₄S₄Cl₄]

LI Ji-Guo¹, LANG Jian-Ping¹, XIN Xin-Quan¹, YU Kai-Bei²

1. Coordination Chemistry Institute, Nanjing University, Nanjing, 210008;
2. Chengdu Center of Analysis and Measurement, Academic Sinica, Chengdu

Received:1991-10-25 Revised:1992-03-23 Online:1992-09-24 Published:1992-09-24

Abstract

Abstract: A violet red solid was obtained by heating the mixture of (NH₄)₂MoS₄,AgCl and (n-Bu)₄NBr in the solid state.The solid was extracted with CH₂Cl₂ to obtain a violet red cubic crystal [(M-Bu)₄N]₃[Mo₄S₄Cl₄].The crystal belongs to the cubic system with space group F43C,a=b=c=2.4212(4) nm,Z=8.The anion core of the title compound can be viewed as a cube skeleton which is composed of four Mo atoms and four Satoms.The distance of Mo-Mo is 0.3154(8) nm.

Key words: Solid state synthesis, Crystal structure, Cluster compound

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LI Ji-Guo, LANG Jian-Ping, XIN Xin-Quan, YU Kai-Bei. Studies on the Solid State Reactions of Coordination Compounds (XLIX)——Solid State Synthesis and Crystal Structure of [(n-Bu)₄N]₃[Mo₄S₄Cl₄][J]. Chem. J. Chinese Universities, 1992, 13(9): 1173.

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Studies on the Solid State Reactions of Coordination Compounds (XLIX)——Solid State Synthesis and Crystal Structure of [(n-Bu)₄N]₃[Mo₄S₄Cl₄]

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