Studies on the System La(ClO4)3-(Glycme(Gly)-H2O(at 25℃)and Crystal Structure of Complex La(Gly)3(ClO4)3·2H2O in the System

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (9): 1157.

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Studies on the System La(ClO₄)₃-(Glycme(Gly)-H₂O(at 25℃)and Crystal Structure of Complex La(Gly)₃(ClO₄)₃·2H₂O in the System

CHEN Jiu-Xiang, RAN Xin-Quan, GUO Zhi-Zhen, CHEN Yun-Sheng

Department of Chemistry, Northwestern University, Xi'an, 710069

Received:1991-09-19 Revised:1992-01-03 Online:1992-09-24 Published:1992-09-24

Abstract

Abstract: The title system was studied,its equilibrium diagram was constructed by solubilities.There were two complexes La(Gly)₃(ClO₄)₃·2H₂O(I) and La(Gly)₄(ClO₄)₃(II) occurring in the system.The incongruent complexes (I) was synthsized,its crystal structure was determined by X-ray diffraction,the structure of (I) consists of [La₂(Gly)₆(H₂O)₄]⁶⁺ cation and perchlotate ions.The crystal is triclinic with space group of P1 The unit cell parameters are as follows:a=1.0693(3) nm,b=1.25956(3) nm,c=0.8762 nm,a=82.83(3)°,β=67.25 (3)° γ=71.50(2)°,forming a distorted tricapped trigonal prism.

Key words: Ternary system, Lanthanum perchloride, Glycine, Crystal structure

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CHEN Jiu-Xiang, RAN Xin-Quan, GUO Zhi-Zhen, CHEN Yun-Sheng . Studies on the System La(ClO₄)₃-(Glycme(Gly)-H₂O(at 25℃)and Crystal Structure of Complex La(Gly)₃(ClO₄)₃·2H₂O in the System[J]. Chem. J. Chinese Universities, 1992, 13(9): 1157.

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Studies on the System La(ClO₄)₃-(Glycme(Gly)-H₂O(at 25℃)and Crystal Structure of Complex La(Gly)₃(ClO₄)₃·2H₂O in the System

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