Synthesis and Crystal Structure of the Two-Electron Reduced Heteropoly Blue of Molybdosilic Acid with α-Keggin Structure

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (8): 1017.

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Synthesis and Crystal Structure of the Two-Electron Reduced Heteropoly Blue of Molybdosilic Acid with α-Keggin Structure

WANG En-Bo¹, ZHANG Lan-Cui¹, WANG Zuo-Ping¹, HUANG Ru-Dan¹, ZHANG Shu-Xia¹, LIN Yong-Hua²

1. Department of Chemistry, Northeast Normal University, Changchun, 130024;
2. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun

Received:1991-08-06 Online:1992-08-24 Published:1992-08-24

Abstract

Abstract: The present paper describes the crystal structure of the title compound H₆SiMo₂^γMo₁₀^иO₁₀·10H₂O prepared by electrolysis.The complex crystallizes in the triclinic space group P1 with a=1.4077(3) nm,b=1.4176(3) nm,c=1.3752(2) nm;α=111.04(1)°,β=93.99(1)°,7=119.09(1)°;Z=2.9005 independent reflections were collected.The structure was solved by direct method and refined by block diagonal-matrix least-squares to R=0.052 for 6287 reflections.The structure of the heteropoly blue retains the original structure of its parent acid basically,but some octahedra change distortedly.

Key words: α-Keggin structure, Heteropoly blue, Crystal structure

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WANG En-Bo, ZHANG Lan-Cui, WANG Zuo-Ping, HUANG Ru-Dan, ZHANG Shu-Xia, LIN Yong-Hua. Synthesis and Crystal Structure of the Two-Electron Reduced Heteropoly Blue of Molybdosilic Acid with α-Keggin Structure[J]. Chem. J. Chinese Universities, 1992, 13(8): 1017.

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Synthesis and Crystal Structure of the Two-Electron Reduced Heteropoly Blue of Molybdosilic Acid with α-Keggin Structure

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