The Synthesis, Crystal Structure and Spectral Properties of 2,2'-Dihydro-2,2'-Bipyridinium Di(triiodide)

Abstract

Abstract: The title compound,(2,2' bipyH₂)(I₃)₂,was prepared and the crystal structure was determined.C₁₀H₁₀NS₂I₆ M=921.65.belongs to triclinic system and space group P1 with a=0-80284(8) nm,b=0.95993(6) nm,c=0.71660(9) nm;α=102.016(9)°,β=111.933(9)° γ=101.650(8)°;V=0.4767(1) nm³,Z=1,D_c=3.21 g·cm^-3,λ(Mo K_a)=0.071069 nm,μ=98.77 cm^-1,F(000)=404.T=296K and final R=0.038 for 1506 observed reflections.The crystal contains [(2,2'-bipyH₂) (I₃)₂]_∞,chains formed by planar trans-(2,2'-bipyH₂)²⁺ cations and linear I3^- anions,between the chains in the same layer there are hydrogen bonds N-H...Iwith N...Idistance of 0.349 nm.Additionally,the title compound was characterized by UV-Vis spectra and ¹H NMR spectra.

Key words: 2,2'-Dihydro-2,2' -bipyridinium cation, Tniodide anion, Crystal structure, UV-Vis spectra, ¹H NMR spectra

TrendMD:

LIU Shi-Xiong, WANG Zhe-Min, ZHANG Bin. The Synthesis, Crystal Structure and Spectral Properties of 2,2'-Dihydro-2,2'-Bipyridinium Di(triiodide)[J]. Chem. J. Chinese Universities, 1992, 13(8): 1013.

References

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