Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (5): 699.

• Articles • Previous Articles     Next Articles

A New Initiator for Group Transfer Polymerization--3-Ethoxy-3-Trimethylsiloxy Acrylonitrile

Xia Hai-ping, Zou You-si, Pan Rong-hua   

  1. Department of Chemistry, Xiamen University, Xiamen, 361005
  • Received:1990-01-16 Online:1991-05-24 Published:1991-05-24

Abstract: The group transfer polymerization (GTP) is a new technique for polymer synthesis. In this paper, Anew GTPinitiator:3-ethoxy-3-trimethylsiloxy acrylonitrile (ETSAN) is reported. It can be synthesized easily:IR,MS,1H and 13CNMR data of ETSAN are reported. The new initiator has a high initiation reactivity. When it initiates acrylonitrile monomer, an explosive polymerization can be observed usually.

Key words: Initiator, Group transfer polymerization, Polyacrylonitrile, Polyacrylate

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