Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (4): 471.

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Molecular and Crystal Structures of (μ-σ,π-Trans-C8H5CH=CH)(μ-C2H5S)Fe2(CO)6

Song Li-cheng1, Hu Qing-mei1, Zhou Zhong-yuan2, Hu Guo-zhi2   

  1. 1. Department of Cliemistry, Nankai University, Tianjin, 300071;
    2. Chengdu Center of Analysis and Determination, Academia Sinica, Chengdu
  • Received:1989-12-07 Online:1991-04-24 Published:1991-04-24

Abstract: (μ-CO)(μ-C2H5S)Fe2(CO)6was prepared from [(μ-CO)(μ-C2H5S)Fe2(CO)6] Et3NH and transor trans-β-C6H5CH=CHBr.Its crystal belong to minoclinic space group Cc.The parameters are:a=1.8053nm,b=1.0436nm,c=1.9045nm;β=93.68°;Dc=1.66g/cm3;Z=8;R=0.0413.Bond Length of Fe-Fe is 0.2542nm.The length of C=C double bond of C=Cdouble bond of C6H5CH=CH ligand is 0. 1358 nm. Ethyl group is attached to bridging sulfur atom by an e-type of bond.

Key words: C6H5CH=CH ligand, C2H5S ligand, Iron carbonyl complex, Crystal structure

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