Synthesis and Crystal Structure of the Complex of Bis[4,4,4-Trifluoro-1-(2-Thienyl) Butanedione-1,3] Copper(Ⅱ) with Diquinoline

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (2): 157.

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Synthesis and Crystal Structure of the Complex of Bis[4,4,4-Trifluoro-1-(2-Thienyl) Butanedione-1,3] Copper(Ⅱ) with Diquinoline

Yu Yun-peng¹, Zhu Duo-lin¹, Xu Zheng², Gou Shao-hua², You Xiao-zeng², Liu Shi-xiong³, Lin Chi-chang³

1. Department of Chemistry, Zhenjiang Teachers' College, Zhenjiang, 212003;
2. Coordination Chemistry Institute, Nanjing University, Nanjing;
3. Institute of Structural Chemistry, Fuzhou Universisty, Fuzhou

Received:1989-04-24 Online:1991-02-24 Published:1991-02-24

Abstract

Abstract: The title compound was synthesized and characterized by elemental analysis, thermo-analy-sis(TG-DTA), 1R and X-ray diffraction analysis.The carystal belongs to triclinic system with a=9. 782(2)Å,6=9. 978(2)Å, c=9. 562(2)Å, α=91.62(2)°, β=111. 09(1)°, γ=104. 75(2)°,V=834. 7A3,Z=1,D_c=1. 52 g·cm^-3,D_m=1.51 g·cm^-3,M=764. 22, F(000)=387e and the space group is P1.The structure was solved by patterson method and refined by least squares method to final R=0. 045 for 2491 reflections. Cu (Ⅱ) is hexacoordinated and lies on the plane formed by four oxygen atoms, two quinoline molecules with Cu(Ⅱ) form the trans-bis-quinoline addut. The plane CuO₄is almost perpendicular to the quinoline ring, the angle between the planes is 93. 8°.

Key words: 4,4,4-Trifluoro-1-(2-thienyl) butanedione-1,3,Quinoline, Copper complex, Crystal structure

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Yu Yun-peng, Zhu Duo-lin, Xu Zheng, Gou Shao-hua, You Xiao-zeng, Liu Shi-xiong, Lin Chi-chang. Synthesis and Crystal Structure of the Complex of Bis[4,4,4-Trifluoro-1-(2-Thienyl) Butanedione-1,3] Copper(Ⅱ) with Diquinoline[J]. Chem. J. Chinese Universities, 1991, 12(2): 157.

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Synthesis and Crystal Structure of the Complex of Bis[4,4,4-Trifluoro-1-(2-Thienyl) Butanedione-1,3] Copper(Ⅱ) with Diquinoline

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