The Electronic Spectra of [M2(η5-C5H5)2(CO)4] with Weak Metal-Metal Bond and M(η5-C5H5)(CO)2Cl(M=Fe,Ru)

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (12): 1640.

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The Electronic Spectra of [M₂(η⁵-C₅H₅)₂(CO)₄] with Weak Metal-Metal Bond and M(η⁵-C₅H₅)(CO)₂Cl(M=Fe,Ru)

Li Zhi-ru, Wang Hai-tao, Li Qian-shu, Li Jun, Feng Ji-kang, Zheng Zhi-ren

Department of Chemistry, Jilin University, Changchun, 130023

Received:1990-09-17 Online:1991-12-24 Published:1991-12-24

Abstract

Abstract: The Electronic Spectra of CMCP(CO)₂]₂and MCp(CO)₂Cl(M=Fe,Ru) are studied by means of INDO/CI method. The calculated values of wave number and transition intensity of the spectra correspond with the experimental results. The bands are assiged and the nature of their charge trasfer is discussed. The blue shift of the same label band with M-Fe,Ru are explained. In addition, the reactions of isomerization and photochemistry are discussed.

Key words: INDO/CI, [M₂(η⁵-C₅H₅)₂(CO)₄], Electronic spectra

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Li Zhi-ru, Wang Hai-tao, Li Qian-shu, Li Jun, Feng Ji-kang, Zheng Zhi-ren . The Electronic Spectra of [M₂(η⁵-C₅H₅)₂(CO)₄] with Weak Metal-Metal Bond and M(η⁵-C₅H₅)(CO)₂Cl(M=Fe,Ru)[J]. Chem. J. Chinese Universities, 1991, 12(12): 1640.

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The Electronic Spectra of [M₂(η⁵-C₅H₅)₂(CO)₄] with Weak Metal-Metal Bond and M(η⁵-C₅H₅)(CO)₂Cl(M=Fe,Ru)

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