Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (7): 667.

• Articles •     Next Articles

Studies on the Solid State Reaction of Coordination Compounds (XXVI) ——Solid State Synthesis and Crystal Structure of Compound WS4Cu3(PPh2)3Cl

Liu Shixiong1, Huang Jinling1, Gao Fengjun2, Zhu Huizhen2, Xin Xinquan2   

  1. 1. Institute of Structural Chemistry, Fuzhou University, Fuzhou;
    2. Coordination Chemistry Institute, Nanjing University, Nanjing
  • Received:1988-10-15 Online:1990-07-24 Published:1990-07-24

Abstract: Abrown-red solid was synthesized through a solid state reaction among (NH4)2WS4, CuCl and PPh3. The solid was extracted with CH2Cl2 and then diffused with CH3OH to obtain a yellow singlecrystal WS4Cu3(PPh3)3Cl. The crystal is triclinic with a = 13. 049(3) Å, b = 20. 351(4) Å, c =11. 876(2) Å, a=94.75(2)°, β=115. 97(1)°, γ=74. 90(2)°, space group P1, z=2. The titlecompound molecule has a cluster core Cu3WS3Cl. The average distance of W- Cu is 2. 719Å.

Key words: Solid state synthesis, Crystal structure

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