Studies on the Structure and Properties of Divalent Metal Aluminophosphate Molecular Sieve

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (4): 331.

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Studies on the Structure and Properties of Divalent Metal Aluminophosphate Molecular Sieve

Han Shuyun¹, Yang Chuncai², Wei Quan², Yuan Hanzhen³

1. Department of Chemistry, Qiugdao University, Qingdao;
2. Department of Chemistry, Jilin University, Changchun;
3. Wuhan Institute of Physics, Academia Sinica, Wuhan

Received:1988-05-09 Online:1990-04-24 Published:1990-04-24

Abstract

Abstract: The pure MeAPO-5 type molecular sieve was synthesized [Me=Mg( Ⅱ ), Fe( Ⅱ ,Ⅲ ), Co ( Ⅱ ), Ni(Ⅱ ), Zn( Ⅱ ), Mn( Ⅱ )] by hydrothermal method. Their ability of adsorption, thermal stability and structure were also investigated by means of XRD, IR, XPS, ESR, Mossbauer, electron probe and MAS NMR. The results show that the structure of MeAPO-5 molecular sieve are AlPO₄-5 type and Metal atom enters the framework of MeAPO-5 molecular sieve.

Key words: Molecular sieve, Metal aluminophosphate, Structure, Property

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Han Shuyun, Yang Chuncai, Wei Quan, Yuan Hanzhen. Studies on the Structure and Properties of Divalent Metal Aluminophosphate Molecular Sieve[J]. Chem. J. Chinese Universities, 1990, 11(4): 331.

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Studies on the Structure and Properties of Divalent Metal Aluminophosphate Molecular Sieve

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