An Electrochemical Study on Binuclear Big Bird Complexes of Ni( Ⅱ ) and Cu( Ⅱ )

Abstract

Abstract: We studied by cyclic voltammetry the oxidation-reduction process of binuclear Big Bird complexes of Ni( Ⅱ ) and Cu( Ⅱ ). Big Bird ligand was synthesized by condensation of tert-buty 1-2,6-diformyl-phenol with 4-n- hexyl- thiourea. The interaction between two central atoms in binuclear complexes and their rate constants of electrode reaction were also investigated. Activation of COby Ni( Ⅱ ) complex was verified by IRand cyclic voltammetry.

Key words: Copper(Ⅱ), Nickel(Ⅱ), Cyclicyvoltammetry, Binuclear Big Bird complex, Carbon monoxide

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Luo Qinhui, Yang Sheng, Shen Mengctutng, Peng Qingyun . An Electrochemical Study on Binuclear Big Bird Complexes of Ni( Ⅱ ) and Cu( Ⅱ )[J]. Chem. J. Chinese Universities, 1990, 11(3): 271.

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An Electrochemical Study on Binuclear Big Bird Complexes of Ni( Ⅱ ) and Cu( Ⅱ )

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