Coordination and Crystal Structure of β-Ketoanilides

doi:10.3969/j.issn.0251-0790.2012.08.020

Abstract

Abstract: β-Ketoanilide derivatives are useful ligands with variable coordination. To identify the exact coordinating sites of complexes formed by β-ketoanilide derivatives and cupric cation, six β-ketoanilide ligands were synthesized and reacted with copper(Ⅱ) acetate, respectively. The yielding complexes were cultivated in various solvents and expected to form single crystals. Only the single crystal Cu(L₆)₂, a Cu(Ⅱ) complex of 2-benzoylacetanilide, was obtained and characterized by single crystal X-ray diffraction. The results showed that Cu(L₆)₂ crystallized into the monoclinic space group P2(1)/c with a=1.3064(7) nm, b=0.4822(3) nm, c=2.0140(10) nm, α=90.00º, β=106.079(9)º, γ=90.00º. Four oxygen atoms from two ligands coordinated a cupric cation and neither copper-carbon bond nor copper-nitrogen bond was found. The existence of non-classical intramolecular C-H…O hydrogen bonds, intermolecular N-H…O hydrogen bonds and π-π stacking were observed.

Key words: β-Ketoanilide, Copper(Ⅱ) complex, Crystal structure

CLC Number:

O625

TrendMD:

CHAI Wei, LI Yue-Jie, XIE Zhuo-Feng, HUANG Yao-Dong, CHANG Ji-Young. Coordination and Crystal Structure of β-Ketoanilides[J]. Chem. J. Chinese Universities, 2012, 33(08): 1738.

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