Determination of Equilibrium Constants for the Adductive Reaction of Bis-(O,O'-Dicyclohexyl-Dithiophosphato) Nickel(Ⅱ) with Pyridine and the Crystal Structure of Ni[(C6H11O)2PS2]2·2Py

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (12): 1225.

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Determination of Equilibrium Constants for the Adductive Reaction of Bis-(O,O'-Dicyclohexyl-Dithiophosphato) Nickel(Ⅱ) with Pyridine and the Crystal Structure of Ni[(C₆H₁₁O)₂PS₂]₂·2Py

Liu Shixiong¹, Lin Xichang¹, Xu Zheng², Lin Jianhua², Yu Yunpeng², You Xiaozeng²

1. Institute of Structural Chemistry, Fuzhou University, Fuzhou;
2. Coordination Chemistry Institute, Nanjing University, Nanjing

Received:1988-03-28 Online:1989-12-24 Published:1989-12-24

Abstract

Abstract: Reaction of Ni[(C₆H₁₁O)₂PS₂]₂ with pyridine was studied spectrophotometrically and the equilibrium constants was found to be k=15.4±1.40(mol/L)-1 and β₂=(1.43±0.41)× 10³ (mol/L)^-2.The crystal structure of Ni[(C₆H₁₁O)₂PS₂]₂.2Py was measured by X-ray diffraction method.The crystal belongs to a monoclinic system with the parameters of unit cell a=8.938(3)Å，b=19.885(6)Å, c=6.366(3)Å,a=99.25(4)°,β=93.96(4)°, γ=92.01(3)°,V=787Å³, D_c= 1.70 g·cm^-3, Z= 1, F(000)=426e.Space group is P₁ R=0.085.

Key words: Dialkyldithiophosphate, Nickel(Ⅱ) coordination compounds, Crystal structure, Adductive equilibrium constant

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Liu Shixiong, Lin Xichang, Xu Zheng, Lin Jianhua, Yu Yunpeng, You Xiaozeng. Determination of Equilibrium Constants for the Adductive Reaction of Bis-(O,O'-Dicyclohexyl-Dithiophosphato) Nickel(Ⅱ) with Pyridine and the Crystal Structure of Ni[(C₆H₁₁O)₂PS₂]₂·2Py[J]. Chem. J. Chinese Universities, 1989, 10(12): 1225.

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Determination of Equilibrium Constants for the Adductive Reaction of Bis-(O,O'-Dicyclohexyl-Dithiophosphato) Nickel(Ⅱ) with Pyridine and the Crystal Structure of Ni[(C₆H₁₁O)₂PS₂]₂·2Py

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