The Synthesis of 7 Meso-Tetrasubstituted Porphyrins

Abstract

Abstract: In this paper, the synthesis of 7 meso-tetrasubstituted porphyrins is reported, five of which are new compounds.These new compounds are-mesa-tetrakis(3-methoxy-4-carboxymethoxyphenyl) porphyrin(B), meso-tetrakis(3-morpholinomethyl-4-methoxyphenyl)porphyrin(C), meso-tetrakis[3-(N,N-diethylaminomethyl)-4-methoxyphenyl] porphyrin (D), meso-tetrakis (3-piperidinomethyl-4-methoxyphenyl) porphyrin (E) and meso-tetrakis (3-pyrrolidinomethyl-4-methoxyphenyl) porphyrin (F).Four new substituted benzaldehydes with morpholino-,diethylamino-, piperidino-and pyrrolidi-no-groups are also prepared.

Key words: Condensation reaction, Intermediate, Nuclear magnetic resonance, Porphyrins, Substitution reaction

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Zhang Zhoupeng, Xu Deyu, Wang Shaoyin . The Synthesis of 7 Meso-Tetrasubstituted Porphyrins[J]. Chem. J. Chinese Universities, 1989, 10(11): 1136.

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The Synthesis of 7 Meso-Tetrasubstituted Porphyrins

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