Chem. J. Chinese Universities

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Submicron spheres Eu2O3/B4C/HDPE composites and properties of neutron and gamma radiation shielding

ZHANG Jie1,2, HUO Zhipeng2, ZHONG Guoqiang2   

  1. 1. Science Island Branch, Graduate School of University of Science and Technology of China 2. Institute of Plasma Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences

  • Received:2025-10-15 Revised:2025-11-18 Online First:2025-11-24 Published:2025-11-24
  • Supported by:
    Supported by the Anhui Province Ecological Environment Research Project, China(No.2023hb0017), the University Synergy Innovation Program of Anhui Province, China(No.GXXT-2022-001), the Comprehensive Research Facility for Fusion Technology Program of China(No.2018-000052 73-01-001228) and the Programs of Institute of Energy, Hefei Comprehensive National Science Center, China(Nos.21KZL401, 21KHH105, 21KZS205, 24JYZL01, 24JYJB01)

Abstract: Eu2O3 fillers (Eu2O3-S) is synthesized by homogeneous precipitation method, and a comparative study is conducted with commercial Eu2O3(Eu2O3-C) fillers with irregular morphology and PbO fillers reinforced composite materials. XRD tests show that the synthesized Eu2O3 fillers (Eu2O3-S) are of cubic crystal system, body-centered cubic lattice, Ia3 ?(206) space group. SEM tests show that the synthetic Eu2O3-S fillers have submicron spherical morphologies with uniform particle size, while the commercial Eu2O3-C fillers have micron particles with irregular morphologies. Mechanical tensile tests and DSC tests show that the yield stress and tensile stress of the synthetic Eu2O3-S /B4C/HDPE composite material are 21.3MPa and 21.0MPa respectively, and the melting temperature is 119.7℃, all of which are stronger than those of commercial Eu2O3-C/B4C/HDPE composite material. Neutron and gamma radiation shielding tests show that the submicron sphere Eu2O3-S fillers with uniform particle size have the best dispersion in the HDPE matrix and can enhance the shielding rate of the composite material. The plate with a thickness of 1.5cm has the best neutron shielding rate (43.66%), and its gamma shielding rate is 13.48%, which is close to the comparison composite material with Pb fillers.

Key words: Eu2O3; Composite, Neutron; Gamma, Radiation shielding

CLC Number: 

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