Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (7): 1501.doi: 10.7503/cjcu20180823
• Physical Chemistry • Previous Articles Next Articles
JI Lei*(), GUO Fanzuo, WANG Kehan, WANG Lei
Received:
2018-12-10
Online:
2019-06-28
Published:
2019-07-09
Contact:
JI Lei
E-mail:jileiwipm@163.com
Supported by:
CLC Number:
TrendMD:
JI Lei,GUO Fanzuo,WANG Kehan,WANG Lei. Surfactant-assisted Formation of Nanoporous Pt Particles as Co-catalyst Loaded on P25 and Enhanced Photocatalytic Performance†[J]. Chem. J. Chinese Universities, 2019, 40(7): 1501.
Sample | w(Pt)(%) | w(Ni)(%) | m(P25)/g |
---|---|---|---|
R-P25 | 0 | 0 | 0.2000 |
Pt/P25 | 3.0 | 0 | 0.1940 |
PtNi2/P25 | 3.0 | 1.8 | 0.1904 |
PtNi3/P25 | 3.0 | 2.7 | 0.1886 |
PtNi4/P25 | 3.0 | 3.6 | 0.1868 |
Table 1 Mass fraction of Pt and Ni and dosage of P25 required
Sample | w(Pt)(%) | w(Ni)(%) | m(P25)/g |
---|---|---|---|
R-P25 | 0 | 0 | 0.2000 |
Pt/P25 | 3.0 | 0 | 0.1940 |
PtNi2/P25 | 3.0 | 1.8 | 0.1904 |
PtNi3/P25 | 3.0 | 2.7 | 0.1886 |
PtNi4/P25 | 3.0 | 3.6 | 0.1868 |
Element | Mass fraction(%) | Atomic fraction(%) | ||||
---|---|---|---|---|---|---|
0 min | 15 min | 30 min | 0 min | 15 min | 30 min | |
C | 7.95 | 8.04 | 4.13 | 16.11 | 15.85 | 8.14 |
O | 38.01 | 40.43 | 46.25 | 57.83 | 59.71 | 68.52 |
Ti | 48.91 | 47.76 | 46.37 | 24.85 | 23.81 | 22.94 |
Ni | 1.96 | 0.54 | — | 0.81 | 0.21 | — |
Pt | 3.17 | 3.23 | 3.25 | 0.40 | 0.42 | 0.40 |
Table 2 Elemental composition of sample de-PtNi2(PT30)P25 with different dealloying time
Element | Mass fraction(%) | Atomic fraction(%) | ||||
---|---|---|---|---|---|---|
0 min | 15 min | 30 min | 0 min | 15 min | 30 min | |
C | 7.95 | 8.04 | 4.13 | 16.11 | 15.85 | 8.14 |
O | 38.01 | 40.43 | 46.25 | 57.83 | 59.71 | 68.52 |
Ti | 48.91 | 47.76 | 46.37 | 24.85 | 23.81 | 22.94 |
Ni | 1.96 | 0.54 | — | 0.81 | 0.21 | — |
Pt | 3.17 | 3.23 | 3.25 | 0.40 | 0.42 | 0.40 |
Sample | Specific surface area/(m2·g-1) | Pore volume/(cm3·g-1) | Aperture/nm |
---|---|---|---|
P25 | 49.0 | 0.20 | 16.2 |
Pt/P25 | 49.3 | 0.23 | 20.6 |
PtNi2/P25 | 48.3 | 0.29 | 21.8 |
de-PtNi2/P25 | 50.3 | 0.29 | 23.0 |
PtNi2(PT30)/P25 | 48.6 | 0.38 | 31.4 |
de-PtNi2(PT30)/P25 | 50.4 | 0.38 | 31.3 |
Table 3 Specific surface area, pore volume and average pore diameter of different samples
Sample | Specific surface area/(m2·g-1) | Pore volume/(cm3·g-1) | Aperture/nm |
---|---|---|---|
P25 | 49.0 | 0.20 | 16.2 |
Pt/P25 | 49.3 | 0.23 | 20.6 |
PtNi2/P25 | 48.3 | 0.29 | 21.8 |
de-PtNi2/P25 | 50.3 | 0.29 | 23.0 |
PtNi2(PT30)/P25 | 48.6 | 0.38 | 31.4 |
de-PtNi2(PT30)/P25 | 50.4 | 0.38 | 31.3 |
Fig.7 Photocatalytic degradation of MB in the presence of different catalysts under UV light irradiation(A) a. P25; b. R-P25; c. Pt/P25; d. de-PtNi/P25; e. de-PtNi2/P25; f. de-PtNi3/P25; g. de-PtNi4/P25. (C) a. P25; b. Pt/P25; c. PtNi2(PT30)/P25; d. de-PtNi2(PT0)/P25; e. de-PtNi2(PT15)/P25; f. de-PtNi2(PT20)/P25; g. de-PtNi2(PT30)/P25; h. de-PtNi2(PT35)/P35. (D) a. P25; b. Pt/P25; c. de-PtNi2(P0T)/P25; d. de-PtNi2(P0.17T)/P25; e. de-PtNi2(P0.033T)/P25; f. de-PtNi2(P0.050T)/P25; g. de-PtNi2(P0.067T)/P25.
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