Sodium Alginate Directed Synthesis of ZnFe2O4 with Micro-nano Structure and Its Performance in Lithium Ion Batteries†

doi:10.7503/cjcu20180051

Abstract

Abstract:

In the addition of Sodium alginate as a structure-directing agent, different micro-nano structures of anode materials ZnFe₂O₄/C were synthesized by the hydrothermal method. The structural and morphological properties were investigated by X-ray diffraction(XRD), field emission scanning electron microscopy(SEM), transmission electron microscopy(TEM) and Raman spectroscopy(Raman). The electrochemical performance was examined by galvanostatic charge-discharge test, cyclic voltammograms and electrochemical impedance spectroscopy. The results indicate that dandelion-liked ZnFe₂O₄/C has a reversible capacity of 2100 mA·h/g after 100 cycles at 1000 mA/g. In addition, the role of sodium alginate and the effect of different structures on electrical performance have also been investigated.

Key words: Sodium alginate, Micro-nano structure, Anode material, Lithium-ion battery

CLC Number:

O646

TrendMD:

WANG Qiuxian,LI Kai,YANG Beining,YUE Hongyun,YANG Shuting. Sodium Alginate Directed Synthesis of ZnFe₂O₄ with Micro-nano Structure and Its Performance in Lithium Ion Batteries^†[J]. Chem. J. Chinese Universities, 2018, 39(9): 2039.

Figures/Tables 9

Fig.1 XRD patterns of the materials

Fig.2 SEM images of HZFOA0(A, B), HZFOA2(C, D), HZFOA4(E, F) and HZFOA6(G, H)

Fig.3 TEM(A, C, E, G) and HRTEM(B, D, F, H) images of HZFOA0(A, B), HZFOA2(C, D), HZFOA4(E, F) and HZFOA6(G, H)

Fig.4 Raman spectrum of HZFOA4

Fig.5 Variant combinatorial modality with different contents of SA

Fig.6 Nitrogen adsorption-desorption isotherms(A) and pore size distribution plots(B) of HZFOA0, HZFOA2, HZFOA4 and HZFOA6

Fig.7 Cycling performances of HZFOA0, HZFOA2, HZFOA4, HZFOA6 at 1 A/g with PVDF binder(A) and SA binder(B)

Fig.8 Cycling performance of HZFOA4 with SA binder at different rates(A, B), AC impedance spectra for HZFOA4 after 100 cycles at different rates(C) and CV curves of HZFOA4 for the first three cycles at 0.1 mV/s between 0.005 V and 3 V(D)

Fig.9 CV profiles at various scan rates(0.2—0.8 mV/s)(A), i(V)/v1/2-v1/2 plots used for calculating k1 and k2 at different potentials(B) and capacitive charge storage contributions at a scan rate of 0.4 mV/s(C)

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Sodium Alginate Directed Synthesis of ZnFe₂O₄ with Micro-nano Structure and Its Performance in Lithium Ion Batteries^†

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