Synthesis of Dual-functionalized Ionic Liquid and Application in CO2 Absorption†

doi:10.7503/cjcu20170117

Abstract

Abstract:

A new bifunctional ionic liquid was prepared, characterized and applied in the absorption and desorption of CO₂. First, 1-methoxyethyl-3-methyl imidazolium glycinate([C₃O₁mim][Gly]) was synthesized by two-step method. The molecular structure was characterized and confirmed by ¹H, ¹³C nuclear magnetic resonance(NMR) and Fourier transform infrared(FTIR) spectroscopy. And thermogravimetric(TG) analysis suggested that [C₃O₁mim][Gly] had good thermal stability. Then, compared to monoethanolamine(MEA), the CO₂ absorption capacity of [C₃O₁mim][Gly] was studied in the range of 25—100 ℃ at normal pressure. By computation, the CO₂ absorption capacity can reach 1.26 mol CO₂/mol IL at 40 ℃, which is greatly higher than that of monoethanolamine(0.54 mol CO₂ /mol MEA). And absorption capacity of CO₂ in [C₃O₁mim][Gly] would decrease with the increase of temperature from 40 ℃ to 100 ℃. Furthermore, the ionic liquid exhibited excellent reversibility and CO₂ absorption capacity can be maintained after 5 times of absorption-desorption circulation. Finally, the absorption kinetics of CO₂ in [C₃O₁mim][Gly] was studied at 40 ℃. And Pseudo-second-order model is good to describe CO₂ absorption in [C₃O₁mim][Gly].

Key words: Ionic liquid, Carbon dioxide, Absorption, Kinetic modeling

CLC Number:

O621.4

TrendMD:

SUN Liwei, LUO Jingyi, TANG Shaokun. Synthesis of Dual-functionalized Ionic Liquid and Application in CO₂ Absorption^†[J]. Chem. J. Chinese Universities, 2017, 38(9): 1578.

Figures/Tables 4

Fig.1 FTIR spectum of [C3O1mim][Gly]

Fig.2 TG(a) and DTG(b) curves of [C3O1mim][Gly](A) and [C3O1mim]Cl(B)

Fig.3 CO2 absorption capacity of [C3O1mim]·[Gly] and MEA vs. time at different temperaturesCO2 absorption capacity means the absorbed CO2 mol amount per mol IL.

Fig.4 Effect of [C3O1mim][Gly] reversible CO2 absorptionCO2 absorption capacity means the absorbed CO2 mol amount per mol IL.

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Synthesis of Dual-functionalized Ionic Liquid and Application in CO₂ Absorption^†

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