Lanthanide Metal-organic Frameworks Constructed from Evolution of a C3 Symmetry Ligand: Syntheses,Structures and Luminescent Properties†

doi:10.7503/cjcu20140555

Abstract

Abstract:

A series of 3D lanthanide metal-organic frameworks(MOFs) with similar structure, [Ln(BTMC)(DMF)]·2.5DMF·3H₂O[Ln=La(1), Ce(2), Pr(3), Nd(4), H₃BTMC=N,N',N″-tris(4-carboxyphenyl)-1,3,5-benzenetricarboxamide], has been synthesized under solvothermal conditions. The structures and thermal-stable properties of the four compounds were characterized by single-crystal X-ray diffraction, powder X-ray diffraction(PXRD), Fourier transform infrared(FTIR) spectra and thermal gravimetric(TG) analyses. The capacities of the compounds for capturing metal ions and dyes were investigated by solid state fluorescence spectra carefully, which indicated that after capturing different metal ions the emission peaks of the four compounds were blue-shift and exhibited a high Cr³⁺-specific luminescence enhancement.

Key words: Lanthanide metal-organic framework, Solid state fluorescence, Metal ion recognition

CLC Number:

O614.33

TrendMD:

WANG Shuhua, HU Hanzhen, CHEN Chao, MA Running, ZHANG Ning. Lanthanide Metal-organic Frameworks Constructed from Evolution of a C₃ Symmetry Ligand: Syntheses,Structures and Luminescent Properties^†[J]. Chem. J. Chinese Universities, 2014, 35(10): 2055.

Figures/Tables 7

Fig.1 Coordination environment of the Pr(Ⅲ) ions in compound 3 All the hydrogen atoms were omitted for clarity.

Fig.2 1D oval channels viewed along c axis in the framework of compound 3

Fig.3 Ball and stick schematic representations of 4-connected ligand(pink, A) and 8-connected Pr dimmer(green, B) and schematic representation of (4,8)-connected AlB2 topology(C) of compound 3

Fig.4 Simulated XRD pattern of compound 3(a) and experimental PXRD patterns of compounds 1—4(b—e, respectively)(A) and compound 3 after capturing/adsorbing Eosin(b), La3+(c), Cr3+(d) and methanol(e)(B)

Fig.5 FTIR spectra of compounds 1—4(a—d, respectively)(A) and compound 3 before(a) and after capturing/adsorbing methanol(b), Cr3+(c), La3+(d) and Cu2+(e)(B)

Fig.6 TG curves of compounds 1—4(A) and compound 3 before and after capturing/adsorbing methanol, Cr3+, La3+ and Eosin(B)

Fig.7 Fluorescence emission spectra of ligand BTMC(a) and compounds 1—4(b—e, respectively)(A) and fluorenscence spectra of compounds 1(B), 3(C) and 4(D) with different ions, methyl orange(MO) and Eosin, respectively The inset bar charts represent the intensity changes of the emission with different ions and dyes.

References 17

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Lanthanide Metal-organic Frameworks Constructed from Evolution of a C₃ Symmetry Ligand: Syntheses,Structures and Luminescent Properties^†

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