Postsynthetic Modification of UMCM-1-NH2 and Fluorescence Recognition for Magnesium†

doi:10.7503/cjcu20140692

Abstract

Abstract:

Salicylaldehyde(Sal) was anchored on the pore of UMCM-1-NH₂ by postsynthetic modification of metal-organic frameworks(MOFs) to yield a functionalized MOF with Schiff base group(UMCM-1-Sal). The capturing capacities of UMCM-1-Sal for different metal ions(Mg, Zn, Co, Ni, Cd, Fe, Cu) were investigated by solid state fluorescence spectra which indicated that the luminescence of the compounds after capturing some metal ions were enhanced, and exhibited a high Mg²⁺-specific luminescence enhancement. The results would be helpful for the design and preparation of new fluorescent probes for Magnesium ion.

Key words: Metal-organicframework, Postsynthetic modification, Magnesium ion, Fluorescence

CLC Number:

O614.33

TrendMD:

WANG Shuhua, WANG Pingping, LI Pengfei, ZHANG Ning, CHEN Chao. Postsynthetic Modification of UMCM-1-NH₂ and Fluorescence Recognition for Magnesium^†[J]. Chem. J. Chinese Universities, 2014, 35(12): 2499.

Figures/Tables 11

Scheme 1 Synthetic route of UMCM-1-Sal

Fig.1 1H NMR spectra of UMCM-1-NH2(a) and UMCM-1-Sal(Red)(b) digested in DCl/D2O/DMSO-d6

Fig.2 PXRD patterns of UMCM-1-NH2(a, b) and UMCM-1-Sal(c) a. Simulated; b, c. experimental.

Fig.3 Nitrogen adsorption-desorption isotherms of UMCM-1-NH2(a), UMCM-1-Sal(b) and UMCM-1-Sal-Mg(c)

Fig.4 TG curves of UMCM-1-NH2(a), UMCM-1-Sal(b) and UMCM-1-Sal-Mg(c)

Fig.5 FTIR spectra of UMCM-1-Sal(a) and UMCM-1-Sal-M(b—f) b. UMCM-1-Sal-Mg; c. UMCM-1-Sal-Zn; d. UMCM-1-Sal-Co;e. UMCM-1-Sal-Fe; f. UMCM-1-Sal-Cu.

Table 1 Metal contents in UMCM-1-Sal-M

Metal ion	(%)	(%)	n(UMCM-1-Sal-M)/n(M)
Mg	1.65	23.30	1:1.18
Zn	8.02	25.17	1:1.96
Cd	11.78	23.25	1:1.82
Co	7.22	22.95	1:2.15
Ni	3.78	23.17	1:1.12
Cu	3.09	23.28	1:0.84

Fig.6 Fluorescence emission spectra of UMCM-1-NH2, UMCM-1-Sal, and UMCM-1-Sal with different ions The inset is the enlarged emission spectra of UMCM-1-Sal with Ni(Ⅱ), Co(Ⅱ), Fe(Ⅲ), and Cu(Ⅱ).

Fig.7 Fluorescence emission intensity of the fluorescence emission for UMCM-1-Sal with different metal ions a. Mg; b. Cd; c. Zn; d. Co; e. Ni; f. Fe; g. Cu;h. UMCM-1-NH2; i. UMCM-1-Sal.

Fig.8 Fluorescence emission spectra of UMCM-1-Sal-Mg with different concentration of Mg2+ ions The inset is the enlarged emission spectra of UMCM-1-Sal-Mg with Mg2+ concentration of 10-4, 10-5 and 10-6 mol/L.

Fig.9 Fluorescence intensity as a function of Mg(Ⅱ) ions concentration

References 18

[1]	Zhang D. Q., Prog. Chem., 2009, 21, 715—723
	(张灯青. 化学进展, 2009, 21, 715—723)
[2]	Farruggia G., Iotti S., Prodi L., Montalti M., Zaccheroni N., Savage P. B., Trapani V., Sale P., Wolf F. I., J. Am. Chem. Soc., 2006, 128, 344—350
[3]	Suzuki Y., Komatsu H., Ikeda T., Saito N., Araki S., Citterio D., Hisamoto H., Kitamura Y., Kubota T., Nakagawa J., Oka K., Suzuki K., Anal. Chem., 2002, 74, 1423—1428
[4]	Song K. C., Choi M. G., Ryu D. H., Kim K. N., Chang S. K., Tetrahedron Lett., 2007, 48, 5397—5400
[5]	Furukawa H., Cordova K. E., O’Keeffe M., Yaghi O. M., Science,2013, 341, 974—987
[6]	Yin X. B., An T., Wang Y., Zhang L. J., Chem. Res. Chinese Universities, 2014, 30(1), 1—3
[7]	Tanabe K. K., Cohen S. M., Chem. Soc. Rev., 2011, 40, 498—519
[8]	Cohen S. M., Chem. Rev., 2012, 112, 970—1000
[9]	Chen C., Allen C. A., Cohen S. M., Inorg. Chem., 2011, 50, 10534—10536
[10]	Choi S. B., Seo M. J., Cho M., Kim Y., Jin M. K., Jung D., Choi J., Ahn W., Rowsell J. L. C., Kim J., Cryt. Growth Des., 2007, 7, 2290—2293
[11]	Tanabe K. K., Cohen S. M., Inorg. Chem., 2010, 49, 6766—6774
[12]	Ingleson M. J., Barrio J. P., Guilbaud J., Khimyak Y. Z., Rosseinsky M. J., Chem. Commun., 2008, 2680—2682
[13]	Xu J.G., Wang Z. B., Fluorescence Analysis, Science Press, Beijing, 2006
	(许金钩, 王尊本. 荧光分析法, 北京: 科学出版社, 2006)
[14]	Wang L., Qin W., Tang X., Dou W., Liu W., J. Phys. Chem. A, 2011, 115, 1609—1616
[15]	Wang S. H., Zhang J. M., Chen C., Zheng T. F., Fang X. Z., Chem. J. Chinese Universities, 2011, 32(11), 2468—2472
	(汪淑华, 张金梅, 陈超, 郑腾飞, 方修中. 高等学校化学学报, 2011, 32(11), 2468—2472)
[16]	Ray D., Bharadwaj P. K., Inorg. Chem., 2008, 47, 2252—2254
[17]	Zhao B., Chen X., Cheng P., Liao D., Yan S., Jiang Z., J. Am. Chem. Soc., 2004, 126, 15394—15395
[18]	Li Y. X., Xue M., Guo L. J., Huang L., Chen S. R., Qiu S. L., Chem. Res. Chinese Universities, 2013, 29(2), 196—200

Postsynthetic Modification of UMCM-1-NH₂ and Fluorescence Recognition for Magnesium^†

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