Effect of MgAlZnFe-CO3 LDHs on Fire Retardancy and Mechanical Properties of Intumescent Flame Retardant Poly(butylene succinate) Composites

doi:10.7503/cjcu20130419

Abstract

Abstract:

MgAlZnFe-CO₃ layered double hydroxides(LDHs) with different proportions of metal ions were prepared by the constant pH coprecipitation method. Ammonium polyphosphate(APP), melamine(MA), and MgAlZnFe-CO₃ LDHs were added in poly(butylene succinate) via melt blending to obtain the novel intumescent flame retardant poly(butylene succinate)(IFR-PBS) composites with MgAlZnFe-CO₃ LDHs as a synergistic agent. The synthesized MgAlZnFe-CO₃ LDHs were characterized by X-ray diffraction(XRD), Inductive coupled phasmamass spectrometer(ICP) and scanning electron microscope(SEM). Consequently, the layered structures of the synthesized MgAlZnFe-CO₃ LDHs were observed. The fire retardancy and mechanical properties of the novel IFR-PBS composites were also evaluated. Compared to those of IFR-PBS composites without MgAlZnFe-CO₃ LDHs, the limiting oxygen index(LOI) values of the novel IFR-PBS composites increased from 30% to 35% and the vertical flammability(UL-94) reached V-0 rate when the content of MgAlZnFe-CO₃ LDHs was 1%(the total loading of flame retardant was 20%). Importantly, the tensile strength and flexural strength of the novel IFR-PBS composites could be enhanced by the presence of MgAlZnFe-CO₃ LDHs.

Key words: Poly(butylene succinate), MgAlZnFe-CO₃ LDHs, Intumescent flame retardant, Mechanical property

CLC Number:

O631

TrendMD:

LIU Yue-Jun, MAO Long. Effect of MgAlZnFe-CO₃ LDHs on Fire Retardancy and Mechanical Properties of Intumescent Flame Retardant Poly(butylene succinate) Composites[J]. Chem. J. Chinese Universities, 2013, 34(12): 2903.

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Effect of MgAlZnFe-CO₃ LDHs on Fire Retardancy and Mechanical Properties of Intumescent Flame Retardant Poly(butylene succinate) Composites

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