Surface-enhanced Raman Scattering of Molecules Adsorbed on SnO2 Nanoparticles

doi:10.3969/j.issn.0251-0790.2012.01.023

Abstract

Abstract: Pure SnO₂ nanoparticles were prepared by the sol-hydrothermal method and were employed as surface-enhanced Raman scattering(SERS) active substrates. The relationships between defect levels and SERS effect of SnO₂ nanoparticles were mainly investigated. The strongest SERS signals were observed when the 4-mercaptobenzoic acid molecules were adsorbed on the surface of SnO₂ nanoparticles(hydrothermal pro-duct), with the increase of calcining temperature, the SERS signals became weaker. Transmission electron microscopy, UV-Vis diffuse reflectance spectroscopy, photoluminescence X-ray diffraction and X-ray photoelectron spectroscopy have been employed to investigate the SnO₂ nanoparticles. The results indicated that surface properties of SnO₂, such as surface defects and oxygen vacancies, etc, play important roles in the SERS. The higher is the content of surface defects and oxygen vacancies, the stronger is SERS signals.

Key words: Surface-enhanced Raman scattering(SERS), SnO₂, Charge transfer, 4-Mercaptobenzoic acid

CLC Number:

O641.3

TrendMD:

HOU Jin-Long, JIA Xiang-Fei, XUE Xiang-Xin, CHEN Lei, SONG Wei, XU Wei-Qing, ZHAO Bing. Surface-enhanced Raman Scattering of Molecules Adsorbed on SnO₂ Nanoparticles[J]. Chem. J. Chinese Universities, 2012, 33(01): 139.

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Surface-enhanced Raman Scattering of Molecules Adsorbed on SnO₂ Nanoparticles

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