高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (4): 627.

• 研究简报 • 上一篇    

铁－芳烃络合物光引发剂的吸收光谱研究

陈旭东1, 黄新华1, 陈用烈2, 梁兆熙2   

  1. 1. 西南师范大学化学系, 重庆, 630715;
    2. 中山大学高分子研究所, 广州
  • 收稿日期:1993-04-27 修回日期:1993-07-27 出版日期:1994-04-24 发布日期:1994-04-24
  • 通讯作者: 陈旭东,男,28岁,硕士,讲师.
  • 作者简介:陈旭东,男,28岁,硕士,讲师.
  • 基金资助:

    国家自然科学基金

Study of Adsorption Spectroscopy on Iron-Arene Complex Photoinitiator

CHEN Xu-Dong1, HUANG Xin-Hua1, CHEN Yong-Lie2, LIANG Zhao-Xi2   

  1. 1. Department of Chemistry, Southwest China Normal UnitJersity, Chongqing, 630715;
    2. Institute of Polymer Science, Zhongshan University, Guangzhou, 510275
  • Received:1993-04-27 Revised:1993-07-27 Online:1994-04-24 Published:1994-04-24

PDF (PC)

关键词: 铁－芳烃络合物, 光引发剂, 吸收光谱, 光解

Abstract: The absorption spectroscopy of cyclopentalienyl-cumene iron hexafluorophosphate (Irgacure 261)in four solvents has been studied, the influence of irradiation on Irgacure 261 has been observed.The results show that the initiator can form complexes with acetonitrile and propylene oxide, The kinetics of photolysis of iron-arene complex has been determined,the photolysis reaction of initiator is the first order reaction, the rate constant of photolysis reaction is 0.391 min-1.

Key words: Iron-arene complex, Photoinitiator, Absorption spectroscopy, Photolysis

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