高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (10): 1443.

• 论文 • 上一篇    下一篇

固相配位化学反应研究(LXVII)─固-固相反应合成混配化合物

张蔚玲, 郑丽敏, 雷立旭, 忻新泉   

  1. 南京大学化学系, 配位化学国家重点实验室, 南京, 210008
  • 收稿日期:1994-02-18 修回日期:1994-05-11 出版日期:1994-10-24 发布日期:1994-10-24
  • 通讯作者: 析新泉.
  • 作者简介:张蔚玲,女,23岁,硕士研究生.
  • 基金资助:

    国家自然科学基金;国家教育委员会博士点基金

Studies on the Solid State Reactions of Coordination Compounds(LXVII)─The Synthesis of Mixed Ligand Complexes in Solid State

ZHANG Wei-Ling, ZHENG Li-Min, LEI Li-Xu, XIN Xin-Quan   

  1. Department of Chemistry, Coodination Chemistry State Key Laboratory, Nanjing University, Nanjing 210008
  • Received:1994-02-18 Revised:1994-05-11 Online:1994-10-24 Published:1994-10-24

摘要: 室温或近室温条件下,Co(acac)2(H2O)2与第二配体2,2'-联吡啶、1,10-啡啰啉、8-羟基喹啉、水杨醛肟固相反应得到4个混配化合物,经XRD、IR、UV及元素分析表征了这些产物。

关键词: 混配化合物, 室温固-固反应, 双(乙酰丙酮)二水合钴(II), 8-羟基喹啉, 2, 2-联吡啶

Abstract: The solid state reactions of diaqua bis(acetylacetonate)cobalt(II)[Co(acac)2(H2O)2]with organic ligands:2, 2'-bipyridyl, 1, 10-phenanthroline, 8-quinolinol and salicylaloxime have been investigated at room or near room temperature. The mixed ligand complexes:Co(acac)2(bipy), Co(acac)2(1, 10-phen), Co(acac)2(8-HQ)2·2H2O, Co(acac)·(SAO)(H2O)have been characterized by the results of UV, FTIR, XRDand elementary analyses.

Key words: Mixed ligand complex, Solid state reaction at room temperature, Diaqua bis(acetylacetonate)cobalt(II), 8-Hydroxyquinoline, 2, 2'-bipyridyl

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