高等学校化学学报 ›› 2005, Vol. 26 ›› Issue (6): 1143.

• 研究简报 • 上一篇    下一篇

Ag/TCNQ双层膜传质规律与模型的理论研究

谢亨博, 蒋益明, 郭峰, 刘平, 李劲   

  1. 复旦大学材料系, 上海200433
  • 收稿日期:2004-06-08 出版日期:2005-06-10 发布日期:2005-06-10
  • 通讯作者: 李 劲(1958年出生),男,教授,从事材料与薄膜传质研究.E-mail:jinli@fudan.edu.cn E-mail:jinli@fudan.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:10374015);国家“九七三”计划项目(批准号:2002CB613504);上海市科委纳米专项基金(批准号:0259nm089)资助.

Theoretical Studies on Transport Behavior and Model of Ag/TCNQ Double-layer Thin Film

XIE Heng-Bo, JIANG Yi-Ming, GUO Feng, LIU Ping, Li Jin   

  1. Department of Material Science, Fudan University, Shanghai 200433, China
  • Received:2004-06-08 Online:2005-06-10 Published:2005-06-10

关键词: 薄膜, 传质, 隧穿

Abstract: Ag/TCNQ double-layer films with different thicknesses were prepared on glasses substrate by alternately vacuum deposition of Ag and TCNQ. The metal-organic complex Ag-TCNQ formed through transport at room temperature and in atmosphere environment. The transport behavior in the film was studied by using transmission spectrum to monitor the process. An abnormal accelerated transport phenomenon was observed with the decrease of the thickness of the film, which was different from the parabola law between transport distance and transport time when the film was thicker. Tunneling and non-tunneling models were established respectively based on whether the tunneling condition was met. The theoretical analyses were carried out in detail.

Key words: Thin film, Transport, Tunneling

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