一个具有杂金属链和蜂巢状纳米孔道结构的三维配位聚合物的合成与表征

doi:10.7503/cjcu20170004

高等学校化学学报 ›› 2017, Vol. 38 ›› Issue (9): 1531.doi: 10.7503/cjcu20170004

• 研究论文: 无机化学 • 上一篇下一篇

一个具有杂金属链和蜂巢状纳米孔道结构的三维配位聚合物的合成与表征

徐中轩(), 吕国岭

遵义师范学院化学化工学院, 遵义 563002

收稿日期:2017-01-03 出版日期:2017-09-10 发布日期:2017-08-17
作者简介:联系人简介: 徐中轩, 男, 博士, 副教授, 主要从事配位聚合物研究. E-mail: xuzhongxuan4201@163.com
基金资助:
贵州省教育厅基金(批准号: 2012015)和遵义师范学院博士基金(批准号: 2012BSJJ12)资助

Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels^†

XU Zhongxuan^*(), LÜ Guoling

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi 563002, China

Received:2017-01-03 Online:2017-09-10 Published:2017-08-17
Contact: XU Zhongxuan E-mail:xuzhongxuan4201@163.com
Supported by:
† Supported by the Foundation of Guizhou Education Department, China(No.2012015) and the Doctoral Scientific Fund of Zunyi Normal College, China(No.2012BSJJ12)

摘要/Abstract

摘要：

在溶剂热条件下, 用预先合成的5-羟甲基间苯二甲酸(H₂HIA)与Zn²⁺及K⁺反应构建出1个具有三维开放框架结构的配位聚合物[Zn_0.5K_0.5(HIA)(H₂O)]·xGuest(1). 在配合物1中, Zn²⁺, K⁺与H₂HIA构建出了无限长的杂金属链和具有亲水表面的蜂巢状纳米孔道. 粉末X射线衍射和热失重分析结果表明, 配合物1为纯相, 330 ℃后有机体开始分解. 此外, 对配合物1的荧光性质也进行了研究.

关键词: 5-羟基间苯二甲酸, 杂金属链, 蜂巢状纳米孔道

Abstract:

Using 5-(hydroxymethyl)isophthalic acid(H₂HIA) as the ligand to assemble with Zn²⁺ ion and K⁺ ion, an open 3D coordination polymer named [Zn_0.5K_0.5(HIA)(H₂O)]·xGuest(1) was constructed under solvothermal conditions. Complex 1 contains interesting infinite hetrometallic chains and honeycombed nanochannels. Powder X-ray diffraction(PXRD) and thermogravimetry analyses(TGA) techniques were applied to characterizing complex 1 and the photoluminescent properties of complex 1 were also investigated.

Key words: 5-(Hydroxymethyl)isophthalic acid, Hetrometallic chain, Honeycombed nanochannel

中图分类号:

O614.2

TrendMD:

徐中轩, 吕国岭. 一个具有杂金属链和蜂巢状纳米孔道结构的三维配位聚合物的合成与表征. 高等学校化学学报, 2017, 38(9): 1531.

XU Zhongxuan, LÜ Guoling. Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels^†. Chem. J. Chinese Universities, 2017, 38(9): 1531.

图/表 7

Scheme 1 Synthetic route for ligand H2HIA

Table 1 Crystal data and refinement results for complex 1

Complex	1	Temperature/K	293(2)
Chemical formula	C₉H_5.78K_0.50O_6.08Zn_0.50	Z	36
Formula weight	263.48	Radiation type	Mo Kα
Crystal system	Hexagonal	Absorption coefficient, μ/mm^-1	1.105
Space group	R $3 ˉ$ c	Number of reflections measured	9518
a/nm	2.96075(9)	Number of independent reflections	2938
b/nm	2.96075(9)	R_int	0.0243
c/nm	1.61371(6)	Final R₁/wR(F²)[(I>2σ(I)]	0.0848/0.2971
α/(°)	90.00	Final R₁(all data)	0.0947
β/(°)	90.00	Goodness of fit on F²	1.048
γ/(°)	120.00	CCDC No.	1525258
Unit cell volume/nm³	12.2507(7)

Table 1 Crystal data and refinement results for complex 1

Complex	1	Temperature/K	293(2)
Chemical formula	C₉H_5.78K_0.50O_6.08Zn_0.50	Z	36
Formula weight	263.48	Radiation type	Mo Kα
Crystal system	Hexagonal	Absorption coefficient, μ/mm^-1	1.105
Space group	R $3 ˉ$ c	Number of reflections measured	9518
a/nm	2.96075(9)	Number of independent reflections	2938
b/nm	2.96075(9)	R_int	0.0243
c/nm	1.61371(6)	Final R₁/wR(F²)[(I>2σ(I)]	0.0848/0.2971
α/(°)	90.00	Final R₁(all data)	0.0947
β/(°)	90.00	Goodness of fit on F²	1.048
γ/(°)	120.00	CCDC No.	1525258
Unit cell volume/nm³	12.2507(7)

Fig.1 Coordination environment of ligand HIA2-in complex 1Symmetry codes: a. x-y, x, -z; b. 1/3-x, 2/3-y, 1/3-z.

Fig.2 Infinite hetrometallic chain(A) and honeycombed nanochannels(B) in complex 1Oxygen atoms of —CH2OH groups are shown in blue.

Fig.3 Framework of complex 1 constructed by hexagonal channels

Fig.4 PXRD pattern(A) and TGA curve(B) of complex 1

Fig.5 Fluorescent emission spectra of ligand H2HIA(a) and complex 1(b) in the solid state at room temperature

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一个具有杂金属链和蜂巢状纳米孔道结构的三维配位聚合物的合成与表征

Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels^†

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一个具有杂金属链和蜂巢状纳米孔道结构的三维配位聚合物的合成与表征

Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels†

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Synthesis and Characterization of a 3D Coordination Polymer with Heterometallic Chains and Honeycombed Nanochannels^†