具有四连接网络的单一手性螺旋配位聚合物的合成与结构表征

doi:10.7503/cjcu20170066

高等学校化学学报 ›› 2017, Vol. 38 ›› Issue (10): 1724.doi: 10.7503/cjcu20170066

• 研究论文: 无机化学 • 上一篇下一篇

具有四连接网络的单一手性螺旋配位聚合物的合成与结构表征

徐中轩()

遵义师范学院化学化工学院, 遵义 563002

收稿日期:2017-01-26 出版日期:2017-10-10 发布日期:2017-09-20
作者简介:联系人简介: 徐中轩, 男, 博士, 副教授, 主要从事配位聚合物研究. E-mail:xuzhongxuan4201@163.com
基金资助:
国家自然科学基金(批准号: 21761036)、贵州省教育厅“125”重大专项基金(批准号: 2012015)和遵义师范学院博士基金(批准号: 2012BSJJ12)资助

Synthesis and Structure Characterization of Homochiral Helical Coordination Polymers with 4-Connected Net Based on Lactic Acid Derivatives^†

XU Zhongxuan()

School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi 563002, China

Received:2017-01-26 Online:2017-10-10 Published:2017-09-20
Supported by:
† Supported by the National Natural Science Foundation of China(No.21761036), the “125” Program of Guizhou Education Department, China(No.2012015) and the Doctoral Scientific Fund of Zunyi Normal College, China(No.2012BSJJ12)

摘要/Abstract

摘要：

在水热反应条件下, 使用乳酸衍生物[(R)-H₂CBA和(S)-H₂CBA]和辅助配体1, 4-DIB与Ni²⁺组合, 制备出一对具有dia拓扑网络的单一手性框架材料 [Ni₂((R)-CBA)₂(1,4-DIB)₃(H₂O)₂]·xH₂O(1-D)和[Ni₂((S)-CBA)₂(1,4-DIB)₃(H₂O)₂] ·xH₂O(1-L). 配合物1-D和1-L具有2种由1,4-DIB与Ni²⁺组构建而成的螺旋链以及二重穿插的结构特征. 此外, 对上述配合物进行了粉末X射线衍射、热失重和圆二色谱测试并对结果进行了分析.

关键词: 单一手性金属有机框架, 四连接网络, 二重穿插, 螺旋链

Abstract:

Using lactic acid derivatives (R),(S)-4-(1-carboxyethoxy)benzoic acid[(R)-H₂CBA and (S)-H₂CBA)] and 1,4-di(1H-imidazol-1-yl)benzene(1,4-DIB) ligand to assemble with Ni²⁺ ions, a pair of novel 4-connected homochiral metal-organic frameworks, [Ni₂((R)-CBA)₂(1,4-DIB)₃(H₂O)₂]·xH₂O(1-D) and [Ni₂((S)-CBA)₂(1,4-DIB)₃(H₂O)₂] ·xH₂O(1-L) have been synthesized under hydrothermal conditions. Complexes 1-D and 1-L feature 2-fold interpenetration structure, containing two kinds of helical chains constructed by achiral 1, 4-DIB ligands and Ni²⁺ ions. Moreover, powder X-ray diffraction(PXRD), thermogrtavimetric analysis(TGA) and solid-state circular dichroism(CD) techniques were also applied to investigate the properties of the complexes..

Key words: Homochiral metal-organic framework, 4-Connected net, 2-Fold interpenetration, Helical chain

中图分类号:

O614.2

TrendMD:

徐中轩. 具有四连接网络的单一手性螺旋配位聚合物的合成与结构表征. 高等学校化学学报, 2017, 38(10): 1724.

XU Zhongxuan. Synthesis and Structure Characterization of Homochiral Helical Coordination Polymers with 4-Connected Net Based on Lactic Acid Derivatives^†. Chem. J. Chinese Universities, 2017, 38(10): 1724.

图/表 7

参考文献 43

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Compound	1-D	1-L	Temperature/K	293(2)	293(2)
Chemical formula	C₂₈H₂₄N₆NiO₆	C₂₈H₂₄N₆NiO₆	Radiation type	Mo Kα	Cu Kα
Formula weight	599.24	599.24	Absorption coefficient, μ/mm^-1	0.655	1.267
Crystal system	Monoclinic	Monoclinic	No. of reflections measured	20194	13721
Space group	P2₁	P2₁	No. of independent reflections	13555	9706
a/nm	0.9547(7)	0.95681(2)	R_int	0.0297	0.0247
b/nm	3.072(4)	3.07427(7)	Final R₁ values[I>2σ(I)]	0.0551	0.0437
c/nm	1.0883(9)	1.09127(2)	Final wR(F²) values[I>2σ(I)]	0.1425	0.1240
α/(°)	90.00	90.00	Final R₁ values(all data)	0.0767	0.0486
β/(°)	93.23(2)	93.274(2)	Final wR(F²) values(all data)	0.1583	0.1287
γ/(°)	90.00	90.00	Goodness of fit on F²	1.036	1.042
Unit cell volume/nm³	3.187(5)	3.20472(12)	Flack parameter	0.079(16)	-0.01(3)
Z	2	2	CCDC No.	1528895	1528896

Compound	1-D	1-L	Temperature/K	293(2)	293(2)
Chemical formula	C₂₈H₂₄N₆NiO₆	C₂₈H₂₄N₆NiO₆	Radiation type	Mo Kα	Cu Kα
Formula weight	599.24	599.24	Absorption coefficient, μ/mm^-1	0.655	1.267
Crystal system	Monoclinic	Monoclinic	No. of reflections measured	20194	13721
Space group	P2₁	P2₁	No. of independent reflections	13555	9706
a/nm	0.9547(7)	0.95681(2)	R_int	0.0297	0.0247
b/nm	3.072(4)	3.07427(7)	Final R₁ values[I>2σ(I)]	0.0551	0.0437
c/nm	1.0883(9)	1.09127(2)	Final wR(F²) values[I>2σ(I)]	0.1425	0.1240
α/(°)	90.00	90.00	Final R₁ values(all data)	0.0767	0.0486
β/(°)	93.23(2)	93.274(2)	Final wR(F²) values(all data)	0.1583	0.1287
γ/(°)	90.00	90.00	Goodness of fit on F²	1.036	1.042
Unit cell volume/nm³	3.187(5)	3.20472(12)	Flack parameter	0.079(16)	-0.01(3)
Z	2	2	CCDC No.	1528895	1528896

具有四连接网络的单一手性螺旋配位聚合物的合成与结构表征

Synthesis and Structure Characterization of Homochiral Helical Coordination Polymers with 4-Connected Net Based on Lactic Acid Derivatives^†

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具有四连接网络的单一手性螺旋配位聚合物的合成与结构表征

Synthesis and Structure Characterization of Homochiral Helical Coordination Polymers with 4-Connected Net Based on Lactic Acid Derivatives†

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Synthesis and Structure Characterization of Homochiral Helical Coordination Polymers with 4-Connected Net Based on Lactic Acid Derivatives^†