卤化钙钛矿型纳米晶的光学性能及应用研究进展

doi:10.7503/cjcu20170788

摘要/Abstract

摘要：

本文重点论述了全无机卤化钙钛矿型(ABX₃)纳米晶的光学性能及应用. 介绍了这类纳米晶的制备方法: 常压溶剂热法和离子交换法, 并进一步阐述其光学性能(主要包括光吸收性能和发光性能)及相关应用(主要包括发光二极管和太阳能电池及其在激光材料、光电探测器和光催化剂领域的应用). 这类材料优异的光电性能使其在其它领域也具有潜在的应用价值.

关键词: 钙钛矿, 卤化物, 纳米晶, 光学性能, 光致发光

Abstract:

Halide perovskite-type ABX₃ nanocrystals mainly including the optical properties and applications of all-inorganic ABX₃ nanocrystals were reviewed. First of all, the two preparation methods of atmospheric pressure, solvent heating and ion-exchange process for all-inorganic nanocrystals are reported; then, the optical properties of their absorption and photoluminescence are elaborated in detail; finally, their applications in light emitting diode(LED) and solar cell are emphasically elucidated, and also involving in the fields of laser, photodetector and photocatalysis. In the recent future, the halide perovskite nanocrystals will also definitely exhibit other potential applications owing to the excellent optical and electrical properties.

Key words: Perovskite-phase, Halide, Nanocrystals, Optical property, Photoluminescence

中图分类号:

O614
O646

TrendMD:

嵇天浩, 田颜清. 卤化钙钛矿型纳米晶的光学性能及应用研究进展. 高等学校化学学报, 2018, 39(6): 1113.

JI Tianhao, TIAN Yanqing. Optical Properties and Applications of Halide-perovskite Nanocrystals^†. Chem. J. Chinese Universities, 2018, 39(6): 1113.

图/表 4

Fig.1 Optical absorption spectra of CsPbX3 nanocrystals[28]Copyright from the American Chemical Society.

Fig.2 Effects of halide ions on the band gap and PLQY in CsPbX3[29](A) PL spectra of CsPb(Br∶X)3(X=Cl, I) NCs prepared by anion exchange from CsPbBr3 NCs; (B) PL calibration curves: a targeted emission energy could be obtained by adding a precise amount of halide precursor to a crude solution of CsPbBr3 NCs; (C) PLQY recorded on the exchanged NCs(dots) as well as the directly synthesized NCs(stars). Copyright from the American Chemical Society.

Fig.3 LED structure with 6.27% of EQE value[60] Copyright from the John Wiley and Sons.

Fig.4 Chemical structures of spiro-OMeTAD, HTM1 and HTM2(A) and normalized UV-Vis absorption spectra of HTM1, HTM2 and spiro-OMeTAD in THF solution(B)[64]Copyright from the Royal Society of Chemistry.

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