高等学校化学学报 ›› 2011, Vol. 32 ›› Issue (1): 7.

• 研究快报 • 上一篇    下一篇

基于含萘二胺的具有醚酮结构的高性能聚合物的合成

朱明,刘佰军,刘晓,姜振华   

  1. 吉林大学麦克德尔米德实验室, 长春 130012
  • 收稿日期:2010-09-06 修回日期:2010-11-15 出版日期:2011-01-10 发布日期:2010-12-11
  • 通讯作者: 刘佰军 E-mail:liubj@jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 50973040)和吉林省科技发展计划(批准号: 20090322)资助.

Synthesis of Ether-ketong Linked High-performance PolymersBased on a Naphthylene-containing Diamine

ZHU Ming, LIU Bai-Jun*, LIU Xiao, JIANG Zhen-Hua   

  1. Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China
  • Received:2010-09-06 Revised:2010-11-15 Online:2011-01-10 Published:2010-12-11
  • Contact: LIU Bai-Jun E-mail:liubj@jlu.edu.cn
  • Supported by:

    National Natural Science Foundation of China

摘要: 本文成功制备了新型的1,5-二[4-(4-氨基苯氧基)]苯羰基-2,6-二甲氧基萘大体积单体,并且通过室温反应制得了具有一定分子量的含有酮醚萘结构的聚甲亚胺和聚酰亚胺。新型聚合物具有高Tg,高热稳定性,高模量,良好的溶解性能和成膜性。

关键词: 高性能聚合物, 可溶性, 聚芳醚酮

Abstract: A new naphthylene-containing diamine having a bulky twist structure was synthesized. Under a mild polycondensation reaction, polyazomethine and polyimide containing ether and ketong linkages were readily prepared. The films of two high-performance polymers exhibited high Tg (219 and 274 oC), high moduli, good thermal stability and improved solubility.

Key words: High-performance-polymers, Solubility, Polyaryletherketone

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