高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (2): 338.

• 研究论文 • 上一篇    下一篇

5,10,15,20-四(对氯苯基)卟啉羟基稀土配合物的光谱研究

贾慧颖1, 徐蔚青1, 齐明辉2, 刘国发2, 李小灵1, 赵冰1   

  1. 1. 吉林大学超分子结构与材料教育部重点实验室, 长春 130023;
    2. 吉林大学化学学院, 长春 130023
  • 收稿日期:2003-05-17 出版日期:2004-02-24 发布日期:2004-02-24
  • 通讯作者: 徐蔚青(1957年出生),男,研究员,主要从事纳米材料及分子组装体光谱学研究.E-mail;wqxu@mail.jlu.edu.cn E-mail:wqxu@mail.jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号;20173019,20273022,29975011)资助

Spectral Study of 5,10,15,20-Tetra(p-Chlorophenyl) PorphyrinLanthanide Complexes

JIA Hui-Ying1, XU Wei-Qing1, QI Ming-Hui2, LIU Guo-Fa2, LI Xiao-Ling1, ZHAO Bing1   

  1. 1. Key Laboratory of Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130023, China;
    2. College of Chemistry, Jilin University, Changchun 130023, China
  • Received:2003-05-17 Online:2004-02-24 Published:2004-02-24

摘要: 研究了四(对氯苯基)卟啉及其羟基稀土配合物的紫外-可见光谱、红外光谱和拉曼光谱,对主要谱带进行了经验归属,讨论了中心离子对紫外光谱和共振拉曼光谱结构敏感带频率的影响.

关键词: 卟啉, 紫外-可见光谱, 红外光谱, 共振拉曼光谱

Abstract: The UV-Vis spectra, Infrared spectra and resonance Raman spectra of tetra(para-chlorophenyl)porphyrin and its coordination compounds LnT(%p%-Cl)PPOH(Ln; Tb, Lu, Er, Gd) were measured and investigated respectively. In UV-Vis spectra the effect of rare earth ions were discussed. Metal sensitive bands in IR spectra were found, and the effect of metal ion size on the marker bands frequencies in resonance Raman spectra was also discussed.

Key words: Porphyrin, UV-Vis spectra, Infrared spectra, Resonance Raman spectra

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