高等学校化学学报

高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (2): 355.

• 论文 • 上一篇    下一篇

含3-甲基苯基-2,3-二氮杂萘-1-酮结构聚醚酰胺的合成、表征与性能

朱秀玲, 蹇锡高, 卢冶, 王瑞玲, 张元红   

  1. 大连理工大学高分子材料系, 大连 116012
  • 收稿日期:2001-10-15 出版日期:2003-02-24 发布日期:2003-02-24
  • 通讯作者: 蹇锡高(1946年出生),男,教授,博士生导师,主要从事耐高温高分子材料及功能材料研究.E-mail:jian4616@mai.ldlptt.ln.cn E-mail:jian4616@mai.ldlptt.ln.cn
  • 基金资助:

    国家自然科学基金(批准号:59473019)资助

Synthesis, Characterization and Property of Poly(aryl ether amides) from 2-(4-Aminophenyl)-4-(3-methyl-4-aminophenoxy)-2,3-phthalazinone

ZHU Xiu-Ling, JIAN Xi-Gao, LU Ye, WANG Rui-Ling, ZHANG Yuan-Hong   

  1. Department of Polymer Science & Materials, Dalian University of Technology, Dalian 116012, China
  • Received:2001-10-15 Online:2003-02-24 Published:2003-02-24

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被引次数

31

摘要： 合成了一种新型芳香二胺双-(4-氨基苯基)-4-(3-甲基-4-苯氧基)-2,3-二氮杂萘-1-酮(1)[2-(4-aminophenyl)-4-(3-methyl-4-phenoxy)-2,3-phthalazinone-1,DAMPP].采用Yamazaki体系,二胺(1)能与多种芳香二酸进行溶液亲核缩聚反应,制得一类新型聚芳醚酰胺,其特性粘度为0.40～0.60dL/g;以MS,FTIR和1HNMR等分析手段研究了新型二胺单体及其聚合物的结构;利用DSC和TGA研究了聚合物的耐热性能,结果表明,新型聚芳酰胺具有高的玻璃化转变温度为598～620K,N2气气氛中10%热质量损失温度在673K以上.聚合物2a～2c的表面电阻系数为3.75×1014～9.87×1015Ω,体积电阻系数为1.39×1016～4.09×1016Ω·cm.聚合物在二甲基甲酰胺、1-甲基吡咯烷酮和间甲酚等极性有机溶剂中可溶解,并经浇注得到透明、韧性薄膜.

关键词: 聚芳酰胺, 杂环聚合物, 二氮杂萘, 溶解性

Abstract: A novel aromatic diamine 2-(4-aminophenyl)-4-(3-methyl-4-aminophenoxy)-2,3-phthalazinone-1(1, DAMPP) containing aza heterocycle was synthesized in a higher yield starting from 4-(3-methyl-4-hydroxyphenyl)-2,3-phthalazinone-1(OM-HPPZ) via two steps conveniently. Diamine 1 polymerized with three aryl dicarboxylic acids to prepare a series of new aromatic polyamides in a high yield using Yamazaki phosphorylation method. The synthesized polymer has a high molecular weight with the inherent viscosity in the range of 0.40-0.60 dL/g. They exhibited high glass transition temperatures of 598-620 K and good thermostable properties with the 10% weight loss temperature above 673 K(in nitrogen). The range of their surface resistance coefficients is 5.89×1015-9.87×1015 Ω and the range of volume resistance coefficients is 1.39×1016-4.09×1016 Ω·cm. These polymers were readily soluble in polar solvents such as NMP, DMF and m-cresol etc, clear tough films were cast from their DMAc solutions. The structures of diamine 1 and polymers obtained was confirmed by MS, FTIR and 1HNMR, which are consistent with the designed structure.

Key words: Poly(aryl amide), Heterocyclic polymer, Phthalazinone, Solubility

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