高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (10): 1758.

• 研究简报 • 上一篇    下一篇

铕配合物[C5H5NC16H33][Eu(TTA)4]在改性介孔材料Si-MCM-41孔道中的组装研究

徐庆红1, 李洪武2, 李连生1, 邹永存1, 徐如人1   

  1. 1. 吉林大学无机合成与制备化学国家重点实验室, 长春 130023;
    2. 吉林省交通职业技术学院, 长春 130012
  • 收稿日期:2003-01-09 出版日期:2003-10-24 发布日期:2003-10-24
  • 通讯作者: 李连生(1942年出生),男,教授,主要从事分子筛的合成和组装化学研究.E-mail:lianshengli@jlu.edu.cn E-mail:lianshengli@jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29225102)资助

A Study on Assembly of a Rare Earth Complex [C5H5NC16H33] [Eu(TTA)4] in the Channel of Si-MCM-41

XU Qing-Hong1, LI Hong-Wu2, LI Lian-Sheng1, ZOU Yong-Cun1, XU Ru-Ren1   

  1. 1. Key Laborary of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130023, China;
    2. Jilin Vocational Technology College of Communication, Changchun 130012, China
  • Received:2003-01-09 Online:2003-10-24 Published:2003-10-24

关键词: 稀土配合物, 介孔二氧化硅, MCM-41, 发光

Abstract: It was proved by ICP, fluorescence spectra and N2adsorption that the rare earth complex [C5H5NC16H33] [Eu(TTA)4] is in the channel of Si-MCM-41 in the course of assembly.The rare earth complex of 67.9% is in the channel, suggesting that the assembly of the complex molecular on the mesoporous MCM-41 was carried out mainly in the channel.

Key words: Rare earth complex, Mesoporous silica, MCM-41, Luminescence

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