高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (8): 1431.

• 研究简报 • 上一篇    下一篇

聚苯乙烯二醋酸碘苯的合成及其在缩氨脲去保护基形成羰基化合物反应中的应用

张继振, 朱勍, 黄宪   

  1. 延边大学, 访问学者, 浙江大学西溪校区化学系, 杭州 310028
  • 收稿日期:2000-02-21 出版日期:2001-08-24 发布日期:2001-08-24
  • 通讯作者: 黄宪(1933年出生),男,教授,博士生导师,从事有机合成化学、金属及元素有机化学研究.
  • 基金资助:

    国家自然科学基金(批准号:29932020)

Synthesis of Poly[styrene(iodoso diacetate)] and Application in Regeneration of Carbonyl Compounds from Semicarbazones

ZHANG Ji-Zhen, ZHU Qing, HUANG Xian   

  1. Department of Chemistry, Xixi Campus of Zhejiang University, Hangzhou 310028, China
  • Received:2000-02-21 Online:2001-08-24 Published:2001-08-24

关键词: 交联聚苯乙烯二醋酸碘苯, 氧化反应, 缩氨脲,

Abstract: The 2% cross-linked poly[styrene(iodoso diacetate)] was synthesized, which was used as oxidative reagent from semicarbazones of ketones to the corresponding ketones in wet acetonitrile under mild conditions, and the possible mechanism was discussed.

Key words: Cross-linked poly[styrene(iodoso diacetate)], Oxidative reaction, Semicarbazones, Ketones

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