高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (3): 347.

• 研究简报 • 上一篇    下一篇

氮氧双自由基桥联双铜(Ê)配合物[Cu(hfac)2]2PhBNOM的合成与晶体结构

赵琦华1, 廖代正1, 姜宗慧1, 阎世平1, 方瑞斌2, 朱红平3   

  1. 1. 南开大学化学系, 天津 300071;
    2. 云南大学化学系, 昆明 650091;
    3. 中国科学院福建物质结构研究所, 福州 350002
  • 收稿日期:1999-09-09 出版日期:2000-03-24 发布日期:2000-03-24
  • 通讯作者: 姜宗慧(1940年出生),女,教授,博士生导师,从事功能配合物研究.
  • 基金资助:

    国家自然科学基金(批准号:29871019,29631040);云南省自然科学基金(批准号:1999B0003M)

Synthesis and Structure of Dinuclear Copper(Ê) Complex with Nitronyl Nitroxide Biradical [Cu(hfac)2]2PhBNOM

ZHAO Qi-Hua1, LIAO Dai-Zheng1, JIANG Zong-Hui1, YAN Shi-Ping1, FANG Rui-Bin2, ZHU Hong-Ping3   

  1. 1. Department of Chemistry, Nankai University, Tianjin 300071, China;
    2. Department of Chemistry, Yunnan University, Kunming 650091, China;
    3. Fujian Instituteof Researchonthe Structure of Matter, Chinese Academyof Sciences, Fuzhou 350002, China
  • Received:1999-09-09 Online:2000-03-24 Published:2000-03-24

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关键词: 氮氧双自由基, 铜(Ê, )配合物, 晶体结构

Abstract: Dinuclear copper complex with biradical, [Cu(hfac)2]2PhBNOM[PhBNOM=2,5-bimethoxyl-1,4-bis(4,4,5,5-tetramethyllimidazoline-1-oxyl-3-oxide)phenyl, hfac=hexafluoroacetylacetonate], has been synthesized and characterized. It crystallized in the monoclinic system; space group C2/c with a = 1.8773(8) nm, b =1.3598(5) nm, c =2.2371(7) nm, β =97.24(3)°, Z =4, R = 0.0961 , Rw=00944 .

Key words: Nitronyl nitroxide biradical, Copper(Ê, ) complex, Crystal structure

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