高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (12): 1987.

• 研究简报 • 上一篇    

聚苯乙烯/蒙脱土纳米复合材料中的剪切诱导有序结构(Ⅰ)--广角X射线衍射与透射电镜研究

陈光明, 漆宗能   

  1. 中国科学院化学研究所工程塑料国家重点实验室, 北京 100080
  • 收稿日期:1999-06-15 出版日期:1999-12-24 发布日期:1999-12-24
  • 通讯作者: 漆宗能
  • 作者简介:陈光明,男,26岁,博士研究生.
  • 基金资助:

    国家自然科学基金重点基金(批准号:59833310)资助课题

A Shear-induced Ordered Structure in PS/Montmorillonite Nanocomposite(Ⅰ)--Wide Angle X-ray Diffraction and Transmission Electron Microscopy Studies

CHEN Guang-Ming, QI Zong-Neng   

  1. State Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
  • Received:1999-06-15 Online:1999-12-24 Published:1999-12-24

关键词: 纳米复合材料, 聚苯乙烯, 蒙脱土, 剪切诱导有序结构

Abstract: A shear-induced ordered structure in PS/montmorillonite nanocomposite was observed for the first time by wide angle X-ray diffraction technique. Atransmission electron microscopy result showed that the randomly placed primary particles of montmorillonite were oriented parallel to the pellet surface, and the interior of the primary particles became more ordered as well. These results suggested that the orientation of the primary particles as well as the interior ordered structure induced by the shear flow were perhaps the origin of the ordered structure in the PS/montmorillonite nanocomposite.

Key words: Nanocomposite, PS,Montmorillonite, Shear-induced ordered structure

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