高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (10): 1590.

• 论文 • 上一篇    下一篇

含位置异构配体的双核铜配合物[CU(μ-CI)(Cl)(C13H10N2S)2]2的合成、表征和晶体结构

郭胜利1, 刘省明1, 殷元骐1, 郁开北2   

  1. 1. 中国科学院兰州化学物理研究所, 兰州 730000;
    2. 中国科学院成都有机化学研究所, 成都 610041
  • 收稿日期:1996-09-10 出版日期:1997-10-24 发布日期:1997-10-24
  • 通讯作者: 殷元骥.
  • 作者简介:郭胜利, 男, 31岁, 博士.
  • 基金资助:

    南京大学配位化学开放实验室资助

Synthesis, Characterization and Crystal Structure of Position-isomer Ligands Contaning Dinuclear Copper(Ⅱ)Complex[CU(μ-Cl)(Cl)(C13H10N2S)2]2

GUO Sheng-Li1, LIU Sheng-Ming1, YIN Yuan-Qi1, YU Kai-Bei2   

  1. 1. Lanzhou Institute of Chemical Physics, Clinese Academy of Sciences, Lanzhou 730000;
    2. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041
  • Received:1996-09-10 Online:1997-10-24 Published:1997-10-24

摘要: 合成了双核铜配合物[Cu(μ-Cl)(Cl)(C13H10N2S)2]2,并对其进行了光谱表征和晶体结构测定.晶体属单斜晶系,空间群P21/n,a=1.3322(2)nm,b=1.5051(2)um,c=1.3591(2)nm;α=γ=90°,β=110.15(1)°,Z=2.在配合物中,每个铜原子与2个桥连氯原子,l个端基氯原子以及2个互为位置异构体的双取代毗唑环上氮原子配位,而使钢原子具有畸变三角双锥构型.

关键词: 双核铜配合物, 位置异构配体, 晶体结构

Abstract: The dinuclear copper(Ⅱ) complex containing position-isomer ligands [Cu (μ-Cl)(Cl) (C13 H10N2S)2]2 was synthesized and characterized by spectroscopy and X-ray crystalstructure determination. The crystal is monoclinic, space group P21/n, with unit celldimensions: a=1. 3322(2) nm, b=1. 5051 (2) nm, c=1. 3591(2) nm; a=γ=90°, β=110. 15(1)°, Z=2, R=0. 0688. Each copper atom is coordinated by two bridged chlorine atom,one terminal chlorine atom and two disubstituted pyrazole position-isomers. So, the copperatom has a distorted trigonal bipyramid configuration.

Key words: Dinuclear copper(Ⅱ) complex, Position-isomer ligand, Crystal structure

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