高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (11): 1729.

• 论文 • 上一篇    下一篇

O-(1-甲硫基乙叉胺基)硫代磷酚胺(酯)的合成及生物活性研究

邢晓东, 贺水济, 许长彪, 田尉, 杨学谨   

  1. 南开大学元素有机化学研究所, 天津, 300071
  • 收稿日期:1995-11-25 出版日期:1996-11-24 发布日期:1996-11-24
  • 通讯作者: 邢晓东,男,57岁,副教授.
  • 作者简介:邢晓东,男,57岁,副教授.

^Advance of Pesticide Research Abroad Synthesis and Properties of O-(1-Methylthioethlieneamino)thiophosphoramidates

XING Xiao-Dong, HE Shui-Ji, XU Chang-Biao, TIAN Wei, YANG Xue-Jin   

  1. Research Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071
  • Received:1995-11-25 Online:1996-11-24 Published:1996-11-24

摘要: 首次报道了甲硫基乙醛肟与硫代磷酰氯的缩合反应,合成了16种新型O-(1-甲硫基乙叉胺基)硫代磷酰胺酯及硫代磷酸酯类化合物,化合物6b具有很好的杀虫活性。

关键词: 甲硫基乙醛肟, 硫代磷酰胺(酯), 波谱性质, 杀虫活性

Abstract: A series of novel O-(1-methylthioethylieneamino)thiophosphoramides were synthesized,and their structures were confirmed by EA,1H NMR,IR and MS.The preliminary tests of pesticidal activities show that two compounds of them have good insecticidal activities.

Key words: Methylthio acetal oxime, Thiophosphoramidate, Spectroscopic properties, Insecticidal activities

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