高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (1): 88.

• 研究简报 • 上一篇    下一篇

乙基苯基二氯化锡与2-羟基萘醛缩对甲氧基苯胺Schiff碱1∶1配合物的合成和晶体结构

刘宝殿1, 包明1, 孙振刚1, 贺庆林1, 邢彦2, 贾恒庆2, 林永华2   

  1. 1. 东北师范大学化学系, 长春 130024;
    2. 中国科学院长春应用化学研究所, 长春
  • 收稿日期:1995-01-18 出版日期:1996-01-24 发布日期:1996-01-24
  • 通讯作者: 刘宝殿
  • 作者简介:刘宝殿,男,55岁,教授.
  • 基金资助:

    吉林省应用基础研究资助

Synthesis and Structure of 1:1 Complex of EthylphenyltinDichloride with N-4-Methoxyphenyl-2-hydroxynaphthylideneimine

LIU Bao-Dian1, BAO Ming1, SUN Zhen-Gang1, HE Qing-Lin1, XING Yan2, JIA Heng-Qing2, LIN Yong-Hua2   

  1. 1. Department of Chemistry, Northeast Nomal University, Changchun 130024;
    2. Changehun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1995-01-18 Online:1996-01-24 Published:1996-01-24

PDF (PC)

被引次数

2

关键词: 乙基苯基二氯化锡, Schiff碱配合物, 晶体结构

Abstract: A novel or ganotin complex,EtPhSnCl2·2HOC10H6CH=NC6H4OCH3 was syn-thesized,and its crystal struct ure was determined by X-ray diffraction method.The crystalis triclinic,belonging to space group P1 with unit cell parameters a=1.1508(5)nm,b=1.1534(5)nm,c=1.0046(3)nm,a=94,15(3)°,β=115.47(3)°,r=85.94(4)°,V=1.1997(1) nm3,Z=2,Dc=1.68 g/cm3,μ=13.20 cm-1,F(000)=618 for 4131 reflections.R=0.047,Rw=0.047.The ligand coordinates to tin atom via phenolic oxygen atom.The complex has a distored trigonal bipyramidal structure,the phenolic oxygen atom of theligand and one of two chlorine atoms occupy the axial position. The distance between non-coodinated nitrogen atom with phenolic oxygen atom is0.2574 nm,which indicates that theintramolecular hydrogen bond of Schiff base ligand is retained in the complex.

Key words: Ethylphenyltin dichloride, Schiff base complex, Crystal structure

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