高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (8): 1146.

• 研究简报 • 上一篇    下一篇

固体表面化学发光法测定微量样品中钴的研究

章竹君, 杨维平, 吕九如   

  1. 陕西师范大学化学系, 西安, 710062
  • 收稿日期:1993-08-04 修回日期:1994-01-10 出版日期:1994-08-24 发布日期:1994-08-24
  • 通讯作者: 章竹君,男,56岁.教授,博士导师.
  • 作者简介:章竹君,男,56岁.教授,博士导师.
  • 基金资助:

    国家自然科学基金

Microanalysis of Cobalt by the Solid Surface Chemiluminesence Technique

ZHANG Zhu-Jun, YANG Wei-Ping, LU Jiu-Ru   

  1. Department of Chemistry, Shaanxi Normal University, Xian, 710062
  • Received:1993-08-04 Revised:1994-01-10 Online:1994-08-24 Published:1994-08-24

PDF (PC)

被引次数

11

关键词: 固体表面发光, 化学发光, 钴, 微量技术

Abstract: Asolid surface chemiluminescence method using the filter paper with anti-permeate barrier as a solid substrate to measure cobalt based on luminol-H2O2-Co(Ⅱ)system is described. The chemiluminescence characteristics of cobalt(Ⅱ) on the solid surface is investigated. The linear range for cobalt is 0.11000 ng. The detection limit is 8 pg/spot, and the relative standard deviation for 0. 1 ng cobalt is 7.2%(n=11). The present method has been successfully applied to the microanalysis of cobalt in the monomineral and steel.

Key words: Solid surface luminescence, Chemiluminescence, Cobalt, Microtechique

TrendMD: