高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (5): 703.

• 研究简报 • 上一篇    下一篇

6,6-二苯基富烯在Cp2TiCl2-i-prMgBr催化下的加氢反应

贺峥杰, 陈寿山   

  1. 南开大学元素有机化学研究所, 天津, 300071
  • 收稿日期:1993-06-01 修回日期:1993-09-20 出版日期:1994-05-24 发布日期:1994-05-24
  • 通讯作者: 陈寿山
  • 作者简介:贺峥杰,男,27岁,博士研究生.
  • 基金资助:

    国家自然科学基金

Catalytic Hydrogenation of 6,6-Diphenylfulvene in the Presence of Cp2TiCl2-i-PrMgBr

HE Zheng-Jie, CHEN Shou-Shan   

  1. Institute of Elemento-organic Chemistry, Nankai University, Tianjin, 300071
  • Received:1993-06-01 Revised:1993-09-20 Online:1994-05-24 Published:1994-05-24

PDF (PC)

关键词: 富烯, 催化氢化, 异构化

Abstract: In this paper,we described catalytic hydrogenation of 6,6-diphenylfulvene in the presence of Cp2TiCl2-i-PrMgBr system under mild conditions,It was found that the low valent titanium catalyst from Cp2TiCl2 and i-prMgBr has a good activity for hydrogenation of the fulvene,and that the catalyst is active for isomerization of adduct hydrogen product.It was also found that there is an obvious gradient velocity of hydrogenation in the reaction.

Key words: 6,6-Diphenylfulvene, Catalytic hydrogenation, Isomerization

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