高等学校化学学报

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (9): 1173.

• 论文 • 上一篇    下一篇

固相配位化学反应研究(XLIX)——[(n-Bu)4N]3[Mo4S4Cl4]的固相合成和晶体结构

李纪国1, 郎建平1, 忻新泉1, 郁开北2   

  1. 1. 南京大学配位化学研究所;
    2. 中国科学院成都分院分析测试中心
  • 收稿日期:1991-10-25 修回日期:1992-03-23 出版日期:1992-09-24 发布日期:1992-09-24
  • 通讯作者: 忻新泉
  • 基金资助:

    国家自然科学基金;国家教委博士点基金

Studies on the Solid State Reactions of Coordination Compounds (XLIX)——Solid State Synthesis and Crystal Structure of [(n-Bu)4N]3[Mo4S4Cl4]

LI Ji-Guo1, LANG Jian-Ping1, XIN Xin-Quan1, YU Kai-Bei2   

  1. 1. Coordination Chemistry Institute, Nanjing University, Nanjing, 210008;
    2. Chengdu Center of Analysis and Measurement, Academic Sinica, Chengdu
  • Received:1991-10-25 Revised:1992-03-23 Online:1992-09-24 Published:1992-09-24

PDF (PC)

关键词: 固相合成, 晶体结构, 簇合物

Abstract: A violet red solid was obtained by heating the mixture of (NH4)2MoS4,AgCl and (n-Bu)4NBr in the solid state.The solid was extracted with CH2Cl2 to obtain a violet red cubic crystal [(M-Bu)4N]3[Mo4S4Cl4].The crystal belongs to the cubic system with space group F43C,a=b=c=2.4212(4) nm,Z=8.The anion core of the title compound can be viewed as a cube skeleton which is composed of four Mo atoms and four Satoms.The distance of Mo-Mo is 0.3154(8) nm.

Key words: Solid state synthesis, Crystal structure, Cluster compound

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