高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (3): 320.

• 研究简报 • 上一篇    下一篇

一种测定反应体系压力变化的无汞反应动力学装置

陈荣悌1, 邓国才1, 郝金库2   

  1. 1. 南开大学化学系;
    2. 天津师范大学化学系
  • 收稿日期:1987-07-18 出版日期:1989-03-24 发布日期:1989-03-24
  • 通讯作者: 陈荣悌

A Kind of Non-Mercury Kinetic Equipment Measuring the Changes in the Pressure of a Reaction System

Chen Rongti1, Deng Guocai1, Hao Jinku2   

  1. 1. Department of Chemistry, Nankai University, Tianjin;
    2. Department of Chemistry, Tianjin Normal University, Tianjin
  • Received:1987-07-18 Online:1989-03-24 Published:1989-03-24

摘要: 测量反应体系压力变化的装置已有报道,但本文装置具有操作方便、记数准确等优点。

关键词: 无汞测压动力学装置, 氢氯化反应, 乙炔

Abstract: A kind of non-mercury kinetic equipment to measure-the changes in the pressure of a reaction system has been designed. Using this equipment, we have studied the kinetics of the reaction of acetylene hydrochlorination in hydrochloric acid with catalyst HgCl2. The reaction apparent activation energy is 58.2kJ/mol. The results showed that the equipment is very convenient to operating and designed to give the accurate recordings.

Key words: Non-mercury kinetic equipment, Hydrochlorination, Acetylene

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